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Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts

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Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts. / Xie, Zhuanzhuan; Akien, Geoffrey Richard; Sarkar, Bibhas R. et al.
In: Industrial and Engineering Chemistry Research, Vol. 54, No. 43, 14.10.2015, p. 10656-10660.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Xie, Z, Akien, GR, Sarkar, BR, Subramaniam, B & Chaudhari, RV 2015, 'Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts', Industrial and Engineering Chemistry Research, vol. 54, no. 43, pp. 10656-10660. https://doi.org/10.1021/acs.iecr.5b02990

APA

Xie, Z., Akien, G. R., Sarkar, B. R., Subramaniam, B., & Chaudhari, R. V. (2015). Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts. Industrial and Engineering Chemistry Research, 54(43), 10656-10660. https://doi.org/10.1021/acs.iecr.5b02990

Vancouver

Xie Z, Akien GR, Sarkar BR, Subramaniam B, Chaudhari RV. Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts. Industrial and Engineering Chemistry Research. 2015 Oct 14;54(43):10656-10660. doi: 10.1021/acs.iecr.5b02990

Author

Xie, Zhuanzhuan ; Akien, Geoffrey Richard ; Sarkar, Bibhas R. et al. / Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts. In: Industrial and Engineering Chemistry Research. 2015 ; Vol. 54, No. 43. pp. 10656-10660.

Bibtex

@article{264fbfab6beb4ad3adffe6cb8c410377,
title = "Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts",
abstract = "Commercially available polydimethylsiloxane (PDMS) was functionalized with phosphine and used to form a Rh complex catalyst. The PDMS-based Rh catalyst complex shows promise as an inexpensive, readily synthesized and nanofilterable homogeneous catalyst for performing continuous hydroformylation. Batch hydroformylation of several substrates including 1-octene, 1-decene, 1-dodecene and styrene showed good activity and selectivity. For 1-octene hydroformylation, the observed catalyst activity with the PDMS-based Rh complex is 2-fold greater compared to that with a conventional Rh-triphenylphosphine complex under similar conditions. Continuous 1-octene hydroformylation for up to 120 h was demonstrated in a membrane nanofiltration system, showing stable conversion (∼60%) and high chemoselectivity (>95%). The total turnover number (TON) after 120 h was approximately 12 000 and the permeate Rh concentration was <2 ppm.",
author = "Zhuanzhuan Xie and Akien, {Geoffrey Richard} and Sarkar, {Bibhas R.} and Bala Subramaniam and Chaudhari, {Raghunath V.}",
year = "2015",
month = oct,
day = "14",
doi = "10.1021/acs.iecr.5b02990",
language = "English",
volume = "54",
pages = "10656--10660",
journal = "Industrial and Engineering Chemistry Research",
issn = "0888-5885",
publisher = "American Chemical Society",
number = "43",

}

RIS

TY - JOUR

T1 - Continuous hydroformylation with phosphine-functionalized polydimethylsiloxane rhodium complexes as nanofilterable homogeneous catalysts

AU - Xie, Zhuanzhuan

AU - Akien, Geoffrey Richard

AU - Sarkar, Bibhas R.

AU - Subramaniam, Bala

AU - Chaudhari, Raghunath V.

PY - 2015/10/14

Y1 - 2015/10/14

N2 - Commercially available polydimethylsiloxane (PDMS) was functionalized with phosphine and used to form a Rh complex catalyst. The PDMS-based Rh catalyst complex shows promise as an inexpensive, readily synthesized and nanofilterable homogeneous catalyst for performing continuous hydroformylation. Batch hydroformylation of several substrates including 1-octene, 1-decene, 1-dodecene and styrene showed good activity and selectivity. For 1-octene hydroformylation, the observed catalyst activity with the PDMS-based Rh complex is 2-fold greater compared to that with a conventional Rh-triphenylphosphine complex under similar conditions. Continuous 1-octene hydroformylation for up to 120 h was demonstrated in a membrane nanofiltration system, showing stable conversion (∼60%) and high chemoselectivity (>95%). The total turnover number (TON) after 120 h was approximately 12 000 and the permeate Rh concentration was <2 ppm.

AB - Commercially available polydimethylsiloxane (PDMS) was functionalized with phosphine and used to form a Rh complex catalyst. The PDMS-based Rh catalyst complex shows promise as an inexpensive, readily synthesized and nanofilterable homogeneous catalyst for performing continuous hydroformylation. Batch hydroformylation of several substrates including 1-octene, 1-decene, 1-dodecene and styrene showed good activity and selectivity. For 1-octene hydroformylation, the observed catalyst activity with the PDMS-based Rh complex is 2-fold greater compared to that with a conventional Rh-triphenylphosphine complex under similar conditions. Continuous 1-octene hydroformylation for up to 120 h was demonstrated in a membrane nanofiltration system, showing stable conversion (∼60%) and high chemoselectivity (>95%). The total turnover number (TON) after 120 h was approximately 12 000 and the permeate Rh concentration was <2 ppm.

U2 - 10.1021/acs.iecr.5b02990

DO - 10.1021/acs.iecr.5b02990

M3 - Journal article

VL - 54

SP - 10656

EP - 10660

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

SN - 0888-5885

IS - 43

ER -