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Control of porosity geometry in amino acid derived nanoporous materials

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Control of porosity geometry in amino acid derived nanoporous materials. / Barrio, Jorge Perez; Rebilly, Jean-Noel; Carter, Benjamin et al.
In: Chemistry - A European Journal, Vol. 14, No. 15, 19.05.2008, p. 4521-4532.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Barrio, JP, Rebilly, J-N, Carter, B, Bradshaw, D, Bacsa, J, Ganin, AY, Park, H, Trewin, A, Vaidhyanathan, R, Cooper, AI, Warren, JE & Rosseinsky, MJ 2008, 'Control of porosity geometry in amino acid derived nanoporous materials', Chemistry - A European Journal, vol. 14, no. 15, pp. 4521-4532. https://doi.org/10.1002/chem.200701556

APA

Barrio, J. P., Rebilly, J.-N., Carter, B., Bradshaw, D., Bacsa, J., Ganin, A. Y., Park, H., Trewin, A., Vaidhyanathan, R., Cooper, A. I., Warren, J. E., & Rosseinsky, M. J. (2008). Control of porosity geometry in amino acid derived nanoporous materials. Chemistry - A European Journal, 14(15), 4521-4532. https://doi.org/10.1002/chem.200701556

Vancouver

Barrio JP, Rebilly JN, Carter B, Bradshaw D, Bacsa J, Ganin AY et al. Control of porosity geometry in amino acid derived nanoporous materials. Chemistry - A European Journal. 2008 May 19;14(15):4521-4532. doi: 10.1002/chem.200701556

Author

Barrio, Jorge Perez ; Rebilly, Jean-Noel ; Carter, Benjamin et al. / Control of porosity geometry in amino acid derived nanoporous materials. In: Chemistry - A European Journal. 2008 ; Vol. 14, No. 15. pp. 4521-4532.

Bibtex

@article{3eb976654f0b44e8bbc2c99b4af6c5c9,
title = "Control of porosity geometry in amino acid derived nanoporous materials",
abstract = "Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The 1D channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their CO2 uptake shows an increase of up to 30% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.",
keywords = "amino acids, chirality, metal-organic frameworks, porous materials, METAL-ORGANIC FRAMEWORKS, COORDINATION POLYMERS, HYDROGEN STORAGE, DESIGN, ADSORPTION, CHIRALITY, LIGAND, SEPARATION, CHEMISTRY, CATALYSIS",
author = "Barrio, {Jorge Perez} and Jean-Noel Rebilly and Benjamin Carter and Darren Bradshaw and John Bacsa and Ganin, {Alexey Y.} and Hyunsoo Park and Abbie Trewin and Ramanathan Vaidhyanathan and Cooper, {Andrew I.} and Warren, {John E.} and Rosseinsky, {Matthew J.}",
year = "2008",
month = may,
day = "19",
doi = "10.1002/chem.200701556",
language = "English",
volume = "14",
pages = "4521--4532",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "15",

}

RIS

TY - JOUR

T1 - Control of porosity geometry in amino acid derived nanoporous materials

AU - Barrio, Jorge Perez

AU - Rebilly, Jean-Noel

AU - Carter, Benjamin

AU - Bradshaw, Darren

AU - Bacsa, John

AU - Ganin, Alexey Y.

AU - Park, Hyunsoo

AU - Trewin, Abbie

AU - Vaidhyanathan, Ramanathan

AU - Cooper, Andrew I.

AU - Warren, John E.

AU - Rosseinsky, Matthew J.

PY - 2008/5/19

Y1 - 2008/5/19

N2 - Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The 1D channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their CO2 uptake shows an increase of up to 30% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.

AB - Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The 1D channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their CO2 uptake shows an increase of up to 30% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.

KW - amino acids

KW - chirality

KW - metal-organic frameworks

KW - porous materials

KW - METAL-ORGANIC FRAMEWORKS

KW - COORDINATION POLYMERS

KW - HYDROGEN STORAGE

KW - DESIGN

KW - ADSORPTION

KW - CHIRALITY

KW - LIGAND

KW - SEPARATION

KW - CHEMISTRY

KW - CATALYSIS

U2 - 10.1002/chem.200701556

DO - 10.1002/chem.200701556

M3 - Journal article

VL - 14

SP - 4521

EP - 4532

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 15

ER -