Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Conversion of furfuryl alcohol into butyl levulinate with graphite oxide and reduced graphite oxide
AU - Gitis, Vitaly
AU - Chung, Sang-Ho
AU - Raveendran, Shiju
PY - 2018/8/15
Y1 - 2018/8/15
N2 - Levulinate esters are important chemical compounds usually obtained by esterification of levulinic acid derived from cellulose. We studied the synthesis of levulinate esters from furfuryl alcohol using graphite oxide (GO) and reduced graphite oxide (rGO) catalysts. The GO and rGO provided close to 100% selectivity to levulinate at a reaction temperature of 110 °C. The reaction rate and selectivity were largely influenced by changing the number of oxygen-containing groups on the catalyst surface. With an increased supply of biomass-derived chemicals, the demonstrated catalytic features of the family of graphite make them good candidates for application in biorefineries.
AB - Levulinate esters are important chemical compounds usually obtained by esterification of levulinic acid derived from cellulose. We studied the synthesis of levulinate esters from furfuryl alcohol using graphite oxide (GO) and reduced graphite oxide (rGO) catalysts. The GO and rGO provided close to 100% selectivity to levulinate at a reaction temperature of 110 °C. The reaction rate and selectivity were largely influenced by changing the number of oxygen-containing groups on the catalyst surface. With an increased supply of biomass-derived chemicals, the demonstrated catalytic features of the family of graphite make them good candidates for application in biorefineries.
U2 - 10.1016/j.flatc.2018.08.002
DO - 10.1016/j.flatc.2018.08.002
M3 - Journal article
VL - 10
SP - 39
EP - 44
JO - FlatChem
JF - FlatChem
SN - 2452-2627
ER -