Standard
Criticality of the [C(4)mim] [BF4] plus water system. / Cerdeirina, CA; Troncoso, [No Value]; Ramos, CP et al.
Ionic liquids III: fundamentals, progress, challenges, and opportunities. ed. / Robin D. Rogers; Kenneth R. Seddon. Washington, D. C.: American Chemical Society, 2005. p. 175-186 (ACS Symposium Series; Vol. 901).
Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Conference contribution/Paper › peer-review
Harvard
Cerdeirina, CA, Troncoso, NV, Ramos, CP, Romani, L
, Najdanovic-Visak, V, Guedes, HJR, Esperanca, JMSS
, Visak, ZP, da Ponte, MN & Rebelo, LPN 2005,
Criticality of the [C(4)mim] [BF4] plus water system. in RD Rogers & KR Seddon (eds),
Ionic liquids III: fundamentals, progress, challenges, and opportunities. ACS Symposium Series, vol. 901, American Chemical Society, Washington, D. C., pp. 175-186, Symposium on Ionic Liquids - Fundamentals, Progress, Challenges and Opportunities held at the 226th American-Chemical-Society National Meeting, New York,
7/09/03.
APA
Cerdeirina, CA., Troncoso, N. V., Ramos, CP., Romani, L.
, Najdanovic-Visak, V., Guedes, HJR., Esperanca, JMSS.
, Visak, ZP., da Ponte, MN., & Rebelo, LPN. (2005).
Criticality of the [C(4)mim] [BF4] plus water system. In R. D. Rogers, & K. R. Seddon (Eds.),
Ionic liquids III: fundamentals, progress, challenges, and opportunities (pp. 175-186). (ACS Symposium Series; Vol. 901). American Chemical Society.
Vancouver
Cerdeirina CA, Troncoso NV, Ramos CP, Romani L
, Najdanovic-Visak V, Guedes HJR et al.
Criticality of the [C(4)mim] [BF4] plus water system. In Rogers RD, Seddon KR, editors, Ionic liquids III: fundamentals, progress, challenges, and opportunities. Washington, D. C.: American Chemical Society. 2005. p. 175-186. (ACS Symposium Series).
Author
Cerdeirina, CA ; Troncoso, [No Value] ; Ramos, CP et al. /
Criticality of the [C(4)mim] [BF4] plus water system. Ionic liquids III: fundamentals, progress, challenges, and opportunities. editor / Robin D. Rogers ; Kenneth R. Seddon. Washington, D. C. : American Chemical Society, 2005. pp. 175-186 (ACS Symposium Series).
Bibtex
@inproceedings{58626bf5b0df4ef5ac6852f3d9c99302,
title = "Criticality of the [C(4)mim] [BF4] plus water system",
abstract = "A study of the behavior of the response functions of the [C(4)mim][BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)(c), is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)(c) is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.",
keywords = "ETHANOL, TEMPERATURE IONIC LIQUIDS, FLUIDS, BEHAVIOR, PRESSURE, CROSSOVER",
author = "CA Cerdeirina and Troncoso, {[No Value]} and CP Ramos and L Romani and Vesna Najdanovic-Visak and HJR Guedes and JMSS Esperanca and ZP Visak and {da Ponte}, MN and LPN Rebelo",
year = "2005",
language = "English",
isbn = "0-8412-3893-6",
series = "ACS Symposium Series",
publisher = "American Chemical Society",
pages = "175--186",
editor = "Rogers, {Robin D.} and Seddon, {Kenneth R.}",
booktitle = "Ionic liquids III",
address = "United States",
note = "Symposium on Ionic Liquids - Fundamentals, Progress, Challenges and Opportunities held at the 226th American-Chemical-Society National Meeting ; Conference date: 07-09-2003 Through 11-09-2003",
}
RIS
TY - GEN
T1 - Criticality of the [C(4)mim] [BF4] plus water system
AU - Cerdeirina, CA
AU - Troncoso, [No Value]
AU - Ramos, CP
AU - Romani, L
AU - Najdanovic-Visak, Vesna
AU - Guedes, HJR
AU - Esperanca, JMSS
AU - Visak, ZP
AU - da Ponte, MN
AU - Rebelo, LPN
PY - 2005
Y1 - 2005
N2 - A study of the behavior of the response functions of the [C(4)mim][BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)(c), is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)(c) is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.
AB - A study of the behavior of the response functions of the [C(4)mim][BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)(c), is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)(c) is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.
KW - ETHANOL
KW - TEMPERATURE IONIC LIQUIDS
KW - FLUIDS
KW - BEHAVIOR
KW - PRESSURE
KW - CROSSOVER
M3 - Conference contribution/Paper
SN - 0-8412-3893-6
T3 - ACS Symposium Series
SP - 175
EP - 186
BT - Ionic liquids III
A2 - Rogers, Robin D.
A2 - Seddon, Kenneth R.
PB - American Chemical Society
CY - Washington, D. C.
T2 - Symposium on Ionic Liquids - Fundamentals, Progress, Challenges and Opportunities held at the 226th American-Chemical-Society National Meeting
Y2 - 7 September 2003 through 11 September 2003
ER -
