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Cryptocatalytic 1,2-alkene migration in a σ-alkyl palladium diene complex

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<mark>Journal publication date</mark>7/08/2009
<mark>Journal</mark>Angewandte Chemie International Edition
Issue number34
Volume48
Number of pages4
Pages (from-to)6262-6265
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Not so simple: A combination of 2H, 13C, and 108Pd labels shows that the alkene migration in a s-alkyl palladium diene complex induced by trifluoromethanesulfonic acid is not intramolecular or acid-mediated, but instead requires a self-generated palladium hydride species (see scheme; Tf=triflate).