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    Rights statement: This is the author’s version of a work that was accepted for publication in Journal of Catalysis. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Catalysis, 335, 2016 DOI: 10.1016/j.jcat.2015.12.027

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Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

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Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. / Montoya, Carmen A.; Gomez, Clara F.; Paninho, Ana B.; Nunes, Ana V.M.; Mahmudov, Kamran T.; Najdanovic, Vesna; Martins, Luisa M.D.R.S.; Guedes da Silva, Fatima C.; Pombiero, Armando J. L.; Nunes da Ponte, Manuel.

In: Journal of Catalysis, Vol. 335, 03.2016, p. 135-140.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Montoya, CA, Gomez, CF, Paninho, AB, Nunes, AVM, Mahmudov, KT, Najdanovic, V, Martins, LMDRS, Guedes da Silva, FC, Pombiero, AJL & Nunes da Ponte, M 2016, 'Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones', Journal of Catalysis, vol. 335, pp. 135-140. https://doi.org/10.1016/j.jcat.2015.12.027

APA

Montoya, C. A., Gomez, C. F., Paninho, A. B., Nunes, A. V. M., Mahmudov, K. T., Najdanovic, V., Martins, L. M. D. R. S., Guedes da Silva, F. C., Pombiero, A. J. L., & Nunes da Ponte, M. (2016). Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. Journal of Catalysis, 335, 135-140. https://doi.org/10.1016/j.jcat.2015.12.027

Vancouver

Montoya CA, Gomez CF, Paninho AB, Nunes AVM, Mahmudov KT, Najdanovic V et al. Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. Journal of Catalysis. 2016 Mar;335:135-140. https://doi.org/10.1016/j.jcat.2015.12.027

Author

Montoya, Carmen A. ; Gomez, Clara F. ; Paninho, Ana B. ; Nunes, Ana V.M. ; Mahmudov, Kamran T. ; Najdanovic, Vesna ; Martins, Luisa M.D.R.S. ; Guedes da Silva, Fatima C. ; Pombiero, Armando J. L. ; Nunes da Ponte, Manuel. / Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones. In: Journal of Catalysis. 2016 ; Vol. 335. pp. 135-140.

Bibtex

@article{567f31d8b4384546bb8f0e17f51d5d2c,
title = "Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones",
abstract = "Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.",
keywords = "Carbon dioxide, Epoxide, Styrene carbonate, Cyclic carbonates, Zinc, Arylhydrazone of B-diketones",
author = "Montoya, {Carmen A.} and Gomez, {Clara F.} and Paninho, {Ana B.} and Nunes, {Ana V.M.} and Mahmudov, {Kamran T.} and Vesna Najdanovic and Martins, {Luisa M.D.R.S.} and {Guedes da Silva}, {Fatima C.} and Pombiero, {Armando J. L.} and {Nunes da Ponte}, Manuel",
note = "This is the author{\textquoteright}s version of a work that was accepted for publication in Journal of Catalysis. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Catalysis, 335, 2016 DOI: 10.1016/j.jcat.2015.12.027",
year = "2016",
month = mar,
doi = "10.1016/j.jcat.2015.12.027",
language = "English",
volume = "335",
pages = "135--140",
journal = "Journal of Catalysis",
issn = "0021-9517",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of β-diketones

AU - Montoya, Carmen A.

AU - Gomez, Clara F.

AU - Paninho, Ana B.

AU - Nunes, Ana V.M.

AU - Mahmudov, Kamran T.

AU - Najdanovic, Vesna

AU - Martins, Luisa M.D.R.S.

AU - Guedes da Silva, Fatima C.

AU - Pombiero, Armando J. L.

AU - Nunes da Ponte, Manuel

N1 - This is the author’s version of a work that was accepted for publication in Journal of Catalysis. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Catalysis, 335, 2016 DOI: 10.1016/j.jcat.2015.12.027

PY - 2016/3

Y1 - 2016/3

N2 - Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.

AB - Zinc(II) complexes of arylhydrazones of β-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.

KW - Carbon dioxide

KW - Epoxide

KW - Styrene carbonate

KW - Cyclic carbonates

KW - Zinc

KW - Arylhydrazone of B-diketones

U2 - 10.1016/j.jcat.2015.12.027

DO - 10.1016/j.jcat.2015.12.027

M3 - Journal article

VL - 335

SP - 135

EP - 140

JO - Journal of Catalysis

JF - Journal of Catalysis

SN - 0021-9517

ER -