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Determination of chlorine containing species in explosive residues using chip-based isotachophoresis

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Determination of chlorine containing species in explosive residues using chip-based isotachophoresis. / Prest, Jeff E.; Beardah, Matthew S.; Baldock, Sara J. et al.

In: Journal of Chromatography A, Vol. 1195, No. 1-2, 27.06.2008, p. 157–163.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Prest, JE, Beardah, MS, Baldock, SJ, Doyle, SP, Fielden, PR, Goddard, NJ & Brown, BJT 2008, 'Determination of chlorine containing species in explosive residues using chip-based isotachophoresis', Journal of Chromatography A, vol. 1195, no. 1-2, pp. 157–163. https://doi.org/10.1016/j.chroma.2008.05.013

APA

Prest, J. E., Beardah, M. S., Baldock, S. J., Doyle, S. P., Fielden, P. R., Goddard, N. J., & Brown, B. J. T. (2008). Determination of chlorine containing species in explosive residues using chip-based isotachophoresis. Journal of Chromatography A, 1195(1-2), 157–163. https://doi.org/10.1016/j.chroma.2008.05.013

Vancouver

Prest JE, Beardah MS, Baldock SJ, Doyle SP, Fielden PR, Goddard NJ et al. Determination of chlorine containing species in explosive residues using chip-based isotachophoresis. Journal of Chromatography A. 2008 Jun 27;1195(1-2):157–163. doi: 10.1016/j.chroma.2008.05.013

Author

Prest, Jeff E. ; Beardah, Matthew S. ; Baldock, Sara J. et al. / Determination of chlorine containing species in explosive residues using chip-based isotachophoresis. In: Journal of Chromatography A. 2008 ; Vol. 1195, No. 1-2. pp. 157–163.

Bibtex

@article{472dc50da1f74fed8c95929b6fac6a9c,
title = "Determination of chlorine containing species in explosive residues using chip-based isotachophoresis",
abstract = "A new method has been developed to allow the determination of the chlorate, chloride and perchlorate anions in inorganic explosive residues to bemadeusing isotachophoresis (ITP). To enable a good separation of these species to be achieved the method involves the use of two complexing agents. Indium(III) is used to allow the determination of chloride whilst using nitrate as the leading ion and -cyclodextrin is used to allow the separation of chlorate and perchlorate. Separations were carried out using a miniaturised poly(methyl methacrylate) (PMMA) separation device. The method was applied to analysing both modelsamples and actual inorganic explosive containing residue samples. Successful determinations of these samples were achieved with no interference from other anions typically found in inorganic explosive residues. Limits of detection (LOD) for the species of interestwere calculated to be 0.80mgl−1 for chloride, 1.75mgl−1 for chlorate and 1.40mgl−1 for perchlorate.",
author = "Prest, {Jeff E.} and Beardah, {Matthew S.} and Baldock, {Sara J.} and Doyle, {Sean P.} and Fielden, {Peter R.} and Goddard, {Nicholas J.} and Brown, {Bernard J. Treves}",
note = "Times Cited: 15 Treves Brown, Bernard/I-3359-2012; Prest, Jeff/L-3089-2013; , Sean/ Treves Brown, Bernard/0000-0001-5696-2944; Prest, Jeff/0000-0001-5307-3949; , Sean/0000-0002-5633-1349 0 15",
year = "2008",
month = jun,
day = "27",
doi = "10.1016/j.chroma.2008.05.013",
language = "English",
volume = "1195",
pages = "157–163",
journal = "Journal of Chromatography A",
issn = "0021-9673",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Determination of chlorine containing species in explosive residues using chip-based isotachophoresis

AU - Prest, Jeff E.

AU - Beardah, Matthew S.

AU - Baldock, Sara J.

AU - Doyle, Sean P.

AU - Fielden, Peter R.

AU - Goddard, Nicholas J.

AU - Brown, Bernard J. Treves

N1 - Times Cited: 15 Treves Brown, Bernard/I-3359-2012; Prest, Jeff/L-3089-2013; , Sean/ Treves Brown, Bernard/0000-0001-5696-2944; Prest, Jeff/0000-0001-5307-3949; , Sean/0000-0002-5633-1349 0 15

PY - 2008/6/27

Y1 - 2008/6/27

N2 - A new method has been developed to allow the determination of the chlorate, chloride and perchlorate anions in inorganic explosive residues to bemadeusing isotachophoresis (ITP). To enable a good separation of these species to be achieved the method involves the use of two complexing agents. Indium(III) is used to allow the determination of chloride whilst using nitrate as the leading ion and -cyclodextrin is used to allow the separation of chlorate and perchlorate. Separations were carried out using a miniaturised poly(methyl methacrylate) (PMMA) separation device. The method was applied to analysing both modelsamples and actual inorganic explosive containing residue samples. Successful determinations of these samples were achieved with no interference from other anions typically found in inorganic explosive residues. Limits of detection (LOD) for the species of interestwere calculated to be 0.80mgl−1 for chloride, 1.75mgl−1 for chlorate and 1.40mgl−1 for perchlorate.

AB - A new method has been developed to allow the determination of the chlorate, chloride and perchlorate anions in inorganic explosive residues to bemadeusing isotachophoresis (ITP). To enable a good separation of these species to be achieved the method involves the use of two complexing agents. Indium(III) is used to allow the determination of chloride whilst using nitrate as the leading ion and -cyclodextrin is used to allow the separation of chlorate and perchlorate. Separations were carried out using a miniaturised poly(methyl methacrylate) (PMMA) separation device. The method was applied to analysing both modelsamples and actual inorganic explosive containing residue samples. Successful determinations of these samples were achieved with no interference from other anions typically found in inorganic explosive residues. Limits of detection (LOD) for the species of interestwere calculated to be 0.80mgl−1 for chloride, 1.75mgl−1 for chlorate and 1.40mgl−1 for perchlorate.

U2 - 10.1016/j.chroma.2008.05.013

DO - 10.1016/j.chroma.2008.05.013

M3 - Journal article

AN - SCOPUS:44649092598

VL - 1195

SP - 157

EP - 163

JO - Journal of Chromatography A

JF - Journal of Chromatography A

SN - 0021-9673

IS - 1-2

ER -