Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Determination of silver in plants by flameless atomic absorption spectrometry and neutron activation analysis
AU - Jones, K. C.
AU - Peterson, P. J.
AU - Davies, B. E.
AU - Minski, M. J.
PY - 1985/8/1
Y1 - 1985/8/1
N2 - Three analytical techniques suitable for determining silver concentrations in plants are presented and compared. Graphite furnace atomic absorption spectrometry performed directly on sample digests was the most sensitive and convenient. Neutron activation analysis, measuring 110mAg gave good reproducibility, but lower sensitivity. A cyclic activation scheme to generate and detect the short-lived isotope 110Ag was useful as a quick reconnaissance technique, but interference from 76As reduced its effectiveness. Data are presented on the silver content of terrestrial plants. Background silver concentrations for lichens and bryophytes collected from Wales, U.K. were 0.07μg g-1. Samples collected from areas contaminated by derelict metal mines contained between 0.1-1.0 μgAg g-1. The aerial portions of vascular species usually contained less silver than bryophytes growing on the same substrate. Fungi are shown to bioconcentrate silver to a greater extent than cadmium, copper or lead.
AB - Three analytical techniques suitable for determining silver concentrations in plants are presented and compared. Graphite furnace atomic absorption spectrometry performed directly on sample digests was the most sensitive and convenient. Neutron activation analysis, measuring 110mAg gave good reproducibility, but lower sensitivity. A cyclic activation scheme to generate and detect the short-lived isotope 110Ag was useful as a quick reconnaissance technique, but interference from 76As reduced its effectiveness. Data are presented on the silver content of terrestrial plants. Background silver concentrations for lichens and bryophytes collected from Wales, U.K. were 0.07μg g-1. Samples collected from areas contaminated by derelict metal mines contained between 0.1-1.0 μgAg g-1. The aerial portions of vascular species usually contained less silver than bryophytes growing on the same substrate. Fungi are shown to bioconcentrate silver to a greater extent than cadmium, copper or lead.
KW - Cyclic activation programme (CAS)
KW - graphite furnace atomic absorption spectrometry (GFAAS)
KW - Neutron activation analysis (NAA)
KW - plants
KW - Silver
U2 - 10.1080/03067318508078368
DO - 10.1080/03067318508078368
M3 - Journal article
AN - SCOPUS:0342539111
VL - 21
SP - 23
EP - 32
JO - International Journal of Environmental Analytical Chemistry
JF - International Journal of Environmental Analytical Chemistry
SN - 0306-7319
IS - 1-2
ER -