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Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation

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Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation. / Sampani, Stavroula I; Aubert, Sidonie; Cattoen, Martin et al.
In: Dalton Transactions, Vol. 47, No. 13, 07.04.2018, p. 44786-4493.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Sampani, SI, Aubert, S, Cattoen, M, Griffiths, K, Abdul-Sada, A, Akien, GR, Tizzard, GJ, Coles, SJ, Arseniyadis, S & Kostakis, GE 2018, 'Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation', Dalton Transactions, vol. 47, no. 13, pp. 44786-4493. https://doi.org/10.1039/c8dt00538a

APA

Sampani, S. I., Aubert, S., Cattoen, M., Griffiths, K., Abdul-Sada, A., Akien, G. R., Tizzard, G. J., Coles, S. J., Arseniyadis, S., & Kostakis, G. E. (2018). Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation. Dalton Transactions, 47(13), 44786-4493. https://doi.org/10.1039/c8dt00538a

Vancouver

Sampani SI, Aubert S, Cattoen M, Griffiths K, Abdul-Sada A, Akien GR et al. Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation. Dalton Transactions. 2018 Apr 7;47(13):44786-4493. Epub 2018 Feb 23. doi: 10.1039/c8dt00538a

Author

Sampani, Stavroula I ; Aubert, Sidonie ; Cattoen, Martin et al. / Dinucleating Schiff base ligand in Zn/4f coordination chemistry : synthetic challenges and catalytic activity evaluation. In: Dalton Transactions. 2018 ; Vol. 47, No. 13. pp. 44786-4493.

Bibtex

@article{c304e8104e4b4490a93bbe037a62fe86,
title = "Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation",
abstract = "Four Zn/4f polynuclear coordination clusters (PCCs) formulated as [ZnDyL2(CO3)2(NO3)2] (1), [ZnIIYIIIL(NO3)2(o-van) (MeOH)] (MeOH) [2 (MeOH)] and [ZnIILnIIIL(NO3)2Cl(EtOH)] where Ln is Dy (3) and Y (4) and where H2L is the dinucleating Schiff base ligand N,N'-bis(3-methoxysalicylidene)cyclohexane-1,2-diamine and o-van is ortho-vanillin, were prepared and fully characterised for the first time. These air-stable heterometallic PCCs, obtained in high yields from commercially available materials, were shown to remain stable in solution in their dinuclear [ZnIILnIIIL] form. Their catalytic activity was evaluated in various catalytic transformations including the Friedel-Crafts alkylation of 2-acyl imidazoles with indoles.",
author = "Sampani, {Stavroula I} and Sidonie Aubert and Martin Cattoen and Kieran Griffiths and Alaa Abdul-Sada and Akien, {Geoffrey R} and Tizzard, {Graham J} and Coles, {Simon J} and Stellios Arseniyadis and Kostakis, {George E}",
note = "This journal is {\textcopyright} The Royal Society of Chemistry 2018",
year = "2018",
month = apr,
day = "7",
doi = "10.1039/c8dt00538a",
language = "English",
volume = "47",
pages = "44786--4493",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "13",

}

RIS

TY - JOUR

T1 - Dinucleating Schiff base ligand in Zn/4f coordination chemistry

T2 - synthetic challenges and catalytic activity evaluation

AU - Sampani, Stavroula I

AU - Aubert, Sidonie

AU - Cattoen, Martin

AU - Griffiths, Kieran

AU - Abdul-Sada, Alaa

AU - Akien, Geoffrey R

AU - Tizzard, Graham J

AU - Coles, Simon J

AU - Arseniyadis, Stellios

AU - Kostakis, George E

N1 - This journal is © The Royal Society of Chemistry 2018

PY - 2018/4/7

Y1 - 2018/4/7

N2 - Four Zn/4f polynuclear coordination clusters (PCCs) formulated as [ZnDyL2(CO3)2(NO3)2] (1), [ZnIIYIIIL(NO3)2(o-van) (MeOH)] (MeOH) [2 (MeOH)] and [ZnIILnIIIL(NO3)2Cl(EtOH)] where Ln is Dy (3) and Y (4) and where H2L is the dinucleating Schiff base ligand N,N'-bis(3-methoxysalicylidene)cyclohexane-1,2-diamine and o-van is ortho-vanillin, were prepared and fully characterised for the first time. These air-stable heterometallic PCCs, obtained in high yields from commercially available materials, were shown to remain stable in solution in their dinuclear [ZnIILnIIIL] form. Their catalytic activity was evaluated in various catalytic transformations including the Friedel-Crafts alkylation of 2-acyl imidazoles with indoles.

AB - Four Zn/4f polynuclear coordination clusters (PCCs) formulated as [ZnDyL2(CO3)2(NO3)2] (1), [ZnIIYIIIL(NO3)2(o-van) (MeOH)] (MeOH) [2 (MeOH)] and [ZnIILnIIIL(NO3)2Cl(EtOH)] where Ln is Dy (3) and Y (4) and where H2L is the dinucleating Schiff base ligand N,N'-bis(3-methoxysalicylidene)cyclohexane-1,2-diamine and o-van is ortho-vanillin, were prepared and fully characterised for the first time. These air-stable heterometallic PCCs, obtained in high yields from commercially available materials, were shown to remain stable in solution in their dinuclear [ZnIILnIIIL] form. Their catalytic activity was evaluated in various catalytic transformations including the Friedel-Crafts alkylation of 2-acyl imidazoles with indoles.

U2 - 10.1039/c8dt00538a

DO - 10.1039/c8dt00538a

M3 - Journal article

C2 - 29505050

VL - 47

SP - 44786

EP - 44493

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 13

ER -