Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst

School of Engineering

Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Conference contribution/Paper › peer-review

Published

Standard

Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. / Olaniyan, B.; Saha, B.
Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. 2019.

Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Conference contribution/Paper › peer-review

Harvard

Olaniyan, B & Saha, B 2019, Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. in Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst.

APA

Olaniyan, B., & Saha, B. (2019). Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. In Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst

Vancouver

Olaniyan B, Saha B. Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. In Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. 2019

Author

Olaniyan, B. ; Saha, B. / Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst. 2019.

Bibtex

@inproceedings{e0671adcbb244a388d2484fbcd7846d1,

title = "Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst",

abstract = "In recent years, CO2 utilisation has been a focus of many chemical industries as an innovative way to reduce the accumulation of anthropogenic CO2. Recent publications show that significant progress has been made in the effective utilisation of CO2 as a value-added products e.g. organic carbonates. Organic carbonates such as propylene carbonate (PC), styrene carbonate (SC) and chloromethyl ethylene carbonate (CMEC) are widely used as polar aprotic solvents, fuel additive and electrolytes for lithium-ion batteries. The development of an efficient and a stable Zr/ZIF-8 catalyst for the synthesis of chloromethyl ethylene carbonate (CMEC) from epichlorohydrin (ECH) and CO2 is a promising greener technology for CO2 utilisation. Incorporating zirconium into ZIF-8 has significantly increased ZIF-8 stability as well as the catalytic performance of Zr/ZIF-8 with the conversion of ECH, selectivity and yield of CMEC being 93%, 91% and 71%, respectively. The catalyst displayed high ECH conversion and high selectivity to CMEC at 80oC. The optimum reaction condition was found at 80oC, 8 bar CO2 pressure and 8 h using fresh 10% (w/w) Zr/ZIF-8 catalyst loading for this reactive system.",

author = "B. Olaniyan and B Saha",

year = "2019",

month = jun,

day = "23",

language = "English",

booktitle = "Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst",

}

RIS

TY - GEN

T1 - Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst

AU - Olaniyan, B.

AU - Saha, B

PY - 2019/6/23

Y1 - 2019/6/23

N2 - In recent years, CO2 utilisation has been a focus of many chemical industries as an innovative way to reduce the accumulation of anthropogenic CO2. Recent publications show that significant progress has been made in the effective utilisation of CO2 as a value-added products e.g. organic carbonates. Organic carbonates such as propylene carbonate (PC), styrene carbonate (SC) and chloromethyl ethylene carbonate (CMEC) are widely used as polar aprotic solvents, fuel additive and electrolytes for lithium-ion batteries. The development of an efficient and a stable Zr/ZIF-8 catalyst for the synthesis of chloromethyl ethylene carbonate (CMEC) from epichlorohydrin (ECH) and CO2 is a promising greener technology for CO2 utilisation. Incorporating zirconium into ZIF-8 has significantly increased ZIF-8 stability as well as the catalytic performance of Zr/ZIF-8 with the conversion of ECH, selectivity and yield of CMEC being 93%, 91% and 71%, respectively. The catalyst displayed high ECH conversion and high selectivity to CMEC at 80oC. The optimum reaction condition was found at 80oC, 8 bar CO2 pressure and 8 h using fresh 10% (w/w) Zr/ZIF-8 catalyst loading for this reactive system.

AB - In recent years, CO2 utilisation has been a focus of many chemical industries as an innovative way to reduce the accumulation of anthropogenic CO2. Recent publications show that significant progress has been made in the effective utilisation of CO2 as a value-added products e.g. organic carbonates. Organic carbonates such as propylene carbonate (PC), styrene carbonate (SC) and chloromethyl ethylene carbonate (CMEC) are widely used as polar aprotic solvents, fuel additive and electrolytes for lithium-ion batteries. The development of an efficient and a stable Zr/ZIF-8 catalyst for the synthesis of chloromethyl ethylene carbonate (CMEC) from epichlorohydrin (ECH) and CO2 is a promising greener technology for CO2 utilisation. Incorporating zirconium into ZIF-8 has significantly increased ZIF-8 stability as well as the catalytic performance of Zr/ZIF-8 with the conversion of ECH, selectivity and yield of CMEC being 93%, 91% and 71%, respectively. The catalyst displayed high ECH conversion and high selectivity to CMEC at 80oC. The optimum reaction condition was found at 80oC, 8 bar CO2 pressure and 8 h using fresh 10% (w/w) Zr/ZIF-8 catalyst loading for this reactive system.

M3 - Conference contribution/Paper

BT - Direct synthesis of chloromethyl ethylene carbonate via CO2 utilisation using a novel Zr/ZIF-8 catalyst

ER -

Research