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Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems: resolution of 2-octanol enantiomers

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Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems: resolution of 2-octanol enantiomers. / Bogel-Lukasik, Rafal; Najdanovic, Vesna; Barreiros, Susana et al.
In: Industrial and Engineering Chemistry Research, Vol. 47, No. 13, 02.07.2008, p. 4473-4480.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Bogel-Lukasik, R, Najdanovic, V, Barreiros, S & da Ponte, MN 2008, 'Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems: resolution of 2-octanol enantiomers', Industrial and Engineering Chemistry Research, vol. 47, no. 13, pp. 4473-4480. https://doi.org/10.1021/ie0714100

APA

Bogel-Lukasik, R., Najdanovic, V., Barreiros, S., & da Ponte, M. N. (2008). Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems: resolution of 2-octanol enantiomers. Industrial and Engineering Chemistry Research, 47(13), 4473-4480. https://doi.org/10.1021/ie0714100

Vancouver

Bogel-Lukasik R, Najdanovic V, Barreiros S, da Ponte MN. Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems: resolution of 2-octanol enantiomers. Industrial and Engineering Chemistry Research. 2008 Jul 2;47(13):4473-4480. doi: 10.1021/ie0714100

Author

Bogel-Lukasik, Rafal ; Najdanovic, Vesna ; Barreiros, Susana et al. / Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems : resolution of 2-octanol enantiomers. In: Industrial and Engineering Chemistry Research. 2008 ; Vol. 47, No. 13. pp. 4473-4480.

Bibtex

@article{7ce11bbd86c943b2af341ea60f1b5469,
title = "Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems: resolution of 2-octanol enantiomers",
abstract = "This paper presents vapor-liquid equilibrium (VLE) data for systems containing high-pressure CO2, an ionic liquid, and products of an enzymatic reaction between succinic anhydride and (R,S)-2-octanol in the presence of a lipase. VLE experiments were used to calculate partition coefficients of reaction products between the ionic liquid-rich phase and the CO2-rich phase. Experiments of extraction with CO2 from an ionic liquid of (S)-2-octanol in conditions similar to those of the postreaction mixture were also carried out. The extraction at 11 MPa and 35 degrees C allows one to recover completely the unreacted enantiomer of 2-octanol with very high enantiomeric excess (98.42%).",
keywords = "PRESSURE PHASE-BEHAVIOR, RACEMIC ALCOHOLS, ORGANIC-SOLVENTS, WATER ACTIVITY, ENHANCED ENANTIOSELECTIVITY, KINETIC RESOLUTION, PRACTICAL RESOLUTION, BIOCATALYSIS, SUCCINIC ANHYDRIDE, CARBON-DIOXIDE",
author = "Rafal Bogel-Lukasik and Vesna Najdanovic and Susana Barreiros and {da Ponte}, {Manuel Nunes}",
year = "2008",
month = jul,
day = "2",
doi = "10.1021/ie0714100",
language = "English",
volume = "47",
pages = "4473--4480",
journal = "Industrial and Engineering Chemistry Research",
issn = "0888-5885",
publisher = "American Chemical Society",
number = "13",

}

RIS

TY - JOUR

T1 - Distribution ratios of lipase-catalyzed reaction products in ionic liquid supercritical CO2 systems

T2 - resolution of 2-octanol enantiomers

AU - Bogel-Lukasik, Rafal

AU - Najdanovic, Vesna

AU - Barreiros, Susana

AU - da Ponte, Manuel Nunes

PY - 2008/7/2

Y1 - 2008/7/2

N2 - This paper presents vapor-liquid equilibrium (VLE) data for systems containing high-pressure CO2, an ionic liquid, and products of an enzymatic reaction between succinic anhydride and (R,S)-2-octanol in the presence of a lipase. VLE experiments were used to calculate partition coefficients of reaction products between the ionic liquid-rich phase and the CO2-rich phase. Experiments of extraction with CO2 from an ionic liquid of (S)-2-octanol in conditions similar to those of the postreaction mixture were also carried out. The extraction at 11 MPa and 35 degrees C allows one to recover completely the unreacted enantiomer of 2-octanol with very high enantiomeric excess (98.42%).

AB - This paper presents vapor-liquid equilibrium (VLE) data for systems containing high-pressure CO2, an ionic liquid, and products of an enzymatic reaction between succinic anhydride and (R,S)-2-octanol in the presence of a lipase. VLE experiments were used to calculate partition coefficients of reaction products between the ionic liquid-rich phase and the CO2-rich phase. Experiments of extraction with CO2 from an ionic liquid of (S)-2-octanol in conditions similar to those of the postreaction mixture were also carried out. The extraction at 11 MPa and 35 degrees C allows one to recover completely the unreacted enantiomer of 2-octanol with very high enantiomeric excess (98.42%).

KW - PRESSURE PHASE-BEHAVIOR

KW - RACEMIC ALCOHOLS

KW - ORGANIC-SOLVENTS

KW - WATER ACTIVITY

KW - ENHANCED ENANTIOSELECTIVITY

KW - KINETIC RESOLUTION

KW - PRACTICAL RESOLUTION

KW - BIOCATALYSIS

KW - SUCCINIC ANHYDRIDE

KW - CARBON-DIOXIDE

U2 - 10.1021/ie0714100

DO - 10.1021/ie0714100

M3 - Journal article

VL - 47

SP - 4473

EP - 4480

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

SN - 0888-5885

IS - 13

ER -