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Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold

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  • Cristina Nieto-Oberhuber
  • Salomé López
  • Maria Munoz-Herranz
  • Diego J. Cárdenas
  • Elena Buñuel
  • Cristina Nevado
  • Antonio M. Echavarren
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<mark>Journal publication date</mark>20/09/2005
<mark>Journal</mark>Angewandte Chemie International Edition
Issue number38
Volume44
Number of pages3
Pages (from-to)6146-6148
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes