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Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores

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Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores. / Al-Yasari, Ahmed; Van Steerteghem, Nick; El Moll, Hani et al.
In: Dalton Transactions, Vol. 45, No. 7, 21.02.2016, p. 2818-2822.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Al-Yasari, A, Van Steerteghem, N, El Moll, H, Clays, K & Fielden, J 2016, 'Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores', Dalton Transactions, vol. 45, no. 7, pp. 2818-2822. https://doi.org/10.1039/C6DT00115G

APA

Al-Yasari, A., Van Steerteghem, N., El Moll, H., Clays, K., & Fielden, J. (2016). Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores. Dalton Transactions, 45(7), 2818-2822. https://doi.org/10.1039/C6DT00115G

Vancouver

Al-Yasari A, Van Steerteghem N, El Moll H, Clays K, Fielden J. Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores. Dalton Transactions. 2016 Feb 21;45(7):2818-2822. doi: 10.1039/C6DT00115G

Author

Al-Yasari, Ahmed ; Van Steerteghem, Nick ; El Moll, Hani et al. / Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores. In: Dalton Transactions. 2016 ; Vol. 45, No. 7. pp. 2818-2822.

Bibtex

@article{1c708308f4f44753a237c36c7f3accd6,
title = "Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores",
abstract = "We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to base high performance 2nd order non-linear optical (NLO) chromophores. This is demonstrated through three new organoimido-Lindqvist derivatives with HRS β0-values exceeding those of any dipolar organic system with comparable donor, π-system and absorption profile. Thus, organoimido POMs may provide a new generation of high performance, high transparency, and potentially redox-switchable NLO materials.",
author = "Ahmed Al-Yasari and {Van Steerteghem}, Nick and {El Moll}, Hani and Koen Clays and John Fielden",
note = "This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.",
year = "2016",
month = feb,
day = "21",
doi = "10.1039/C6DT00115G",
language = "English",
volume = "45",
pages = "2818--2822",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "7",

}

RIS

TY - JOUR

T1 - Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores

AU - Al-Yasari, Ahmed

AU - Van Steerteghem, Nick

AU - El Moll, Hani

AU - Clays, Koen

AU - Fielden, John

N1 - This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

PY - 2016/2/21

Y1 - 2016/2/21

N2 - We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to base high performance 2nd order non-linear optical (NLO) chromophores. This is demonstrated through three new organoimido-Lindqvist derivatives with HRS β0-values exceeding those of any dipolar organic system with comparable donor, π-system and absorption profile. Thus, organoimido POMs may provide a new generation of high performance, high transparency, and potentially redox-switchable NLO materials.

AB - We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to base high performance 2nd order non-linear optical (NLO) chromophores. This is demonstrated through three new organoimido-Lindqvist derivatives with HRS β0-values exceeding those of any dipolar organic system with comparable donor, π-system and absorption profile. Thus, organoimido POMs may provide a new generation of high performance, high transparency, and potentially redox-switchable NLO materials.

U2 - 10.1039/C6DT00115G

DO - 10.1039/C6DT00115G

M3 - Journal article

VL - 45

SP - 2818

EP - 2822

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 7

ER -