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Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses. / Parkinson, B.G.; Holland, D.; Smith, M.E. et al.
In: Journal of Non-Crystalline Solids, Vol. 353, No. 44-46, 15.11.2007, p. 4076-4083.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Parkinson, BG, Holland, D, Smith, ME, Howes, AP & Scales, CR 2007, 'Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses', Journal of Non-Crystalline Solids, vol. 353, no. 44-46, pp. 4076-4083. https://doi.org/10.1016/j.jnoncrysol.2007.06.016

APA

Parkinson, B. G., Holland, D., Smith, M. E., Howes, A. P., & Scales, C. R. (2007). Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses. Journal of Non-Crystalline Solids, 353(44-46), 4076-4083. https://doi.org/10.1016/j.jnoncrysol.2007.06.016

Vancouver

Parkinson BG, Holland D, Smith ME, Howes AP, Scales CR. Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses. Journal of Non-Crystalline Solids. 2007 Nov 15;353(44-46):4076-4083. doi: 10.1016/j.jnoncrysol.2007.06.016

Author

Parkinson, B.G. ; Holland, D. ; Smith, M.E. et al. / Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses. In: Journal of Non-Crystalline Solids. 2007 ; Vol. 353, No. 44-46. pp. 4076-4083.

Bibtex

@article{d09042aeb6514cc0b93878666ef23456,
title = "Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses",
abstract = "Structural and thermal properties are reported for a range of caesium oxide-containing alkali borosilicate glasses, of the form xCs2O(100 - x)ZMW (0 < x < 10), where ZMW represents a variety of simulated base-glasses. Glass densities increase and glass transition temperatures decrease with increase in caesium oxide concentration. Mass-loss from the melt is found to depend on composition in the same manner as the fraction of silicon Q3 units, resolved from 29Si MAS NMR, and is related to the presence of danburite medium-range order units, resolved from 11B MAS NMR. Volatilization is shown to occur even in the absence of caesium oxide and the mixed alkali borosilicate composition of the volatile species, evolved from the melt at high temperature, is independent of the starting composition of the glass. {\textcopyright} 2007 Elsevier B.V. All rights reserved.",
keywords = "Borosilicates, Glasses, Medium-range order, NMR, MAS NMR and NQR, Nuclear and chemical wastes, Nuclear magnetic (and quadrupole) resonance, Oxide glasses, Resonance methods, Structure, Density (specific gravity), Microstructure, Nuclear magnetic resonance, Vaporization, Borosilicate glass",
author = "B.G. Parkinson and D. Holland and M.E. Smith and A.P. Howes and C.R. Scales",
year = "2007",
month = nov,
day = "15",
doi = "10.1016/j.jnoncrysol.2007.06.016",
language = "English",
volume = "353",
pages = "4076--4083",
journal = "Journal of Non-Crystalline Solids",
issn = "0022-3093",
publisher = "Elsevier",
number = "44-46",

}

RIS

TY - JOUR

T1 - Effect of minor additions on structure and volatilization loss in simulated nuclear borosilicate glasses

AU - Parkinson, B.G.

AU - Holland, D.

AU - Smith, M.E.

AU - Howes, A.P.

AU - Scales, C.R.

PY - 2007/11/15

Y1 - 2007/11/15

N2 - Structural and thermal properties are reported for a range of caesium oxide-containing alkali borosilicate glasses, of the form xCs2O(100 - x)ZMW (0 < x < 10), where ZMW represents a variety of simulated base-glasses. Glass densities increase and glass transition temperatures decrease with increase in caesium oxide concentration. Mass-loss from the melt is found to depend on composition in the same manner as the fraction of silicon Q3 units, resolved from 29Si MAS NMR, and is related to the presence of danburite medium-range order units, resolved from 11B MAS NMR. Volatilization is shown to occur even in the absence of caesium oxide and the mixed alkali borosilicate composition of the volatile species, evolved from the melt at high temperature, is independent of the starting composition of the glass. © 2007 Elsevier B.V. All rights reserved.

AB - Structural and thermal properties are reported for a range of caesium oxide-containing alkali borosilicate glasses, of the form xCs2O(100 - x)ZMW (0 < x < 10), where ZMW represents a variety of simulated base-glasses. Glass densities increase and glass transition temperatures decrease with increase in caesium oxide concentration. Mass-loss from the melt is found to depend on composition in the same manner as the fraction of silicon Q3 units, resolved from 29Si MAS NMR, and is related to the presence of danburite medium-range order units, resolved from 11B MAS NMR. Volatilization is shown to occur even in the absence of caesium oxide and the mixed alkali borosilicate composition of the volatile species, evolved from the melt at high temperature, is independent of the starting composition of the glass. © 2007 Elsevier B.V. All rights reserved.

KW - Borosilicates

KW - Glasses

KW - Medium-range order

KW - NMR, MAS NMR and NQR

KW - Nuclear and chemical wastes

KW - Nuclear magnetic (and quadrupole) resonance

KW - Oxide glasses

KW - Resonance methods

KW - Structure

KW - Density (specific gravity)

KW - Microstructure

KW - Nuclear magnetic resonance

KW - Vaporization

KW - Borosilicate glass

U2 - 10.1016/j.jnoncrysol.2007.06.016

DO - 10.1016/j.jnoncrysol.2007.06.016

M3 - Journal article

VL - 353

SP - 4076

EP - 4083

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

SN - 0022-3093

IS - 44-46

ER -