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Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex. / Mbeleck, R.; Mohammed, M.L.; Ambroziak, K. et al.
In: Catalysis Today, Vol. 256, No. 2, 01.11.2015, p. 287-293.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Mbeleck, R, Mohammed, ML, Ambroziak, K, Sherrington, DC & Saha, B 2015, 'Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex', Catalysis Today, vol. 256, no. 2, pp. 287-293. https://doi.org/10.1016/j.cattod.2014.12.029

APA

Mbeleck, R., Mohammed, M. L., Ambroziak, K., Sherrington, D. C., & Saha, B. (2015). Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex. Catalysis Today, 256(2), 287-293. https://doi.org/10.1016/j.cattod.2014.12.029

Vancouver

Mbeleck R, Mohammed ML, Ambroziak K, Sherrington DC, Saha B. Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex. Catalysis Today. 2015 Nov 1;256(2):287-293. Epub 2015 Sept 1. doi: 10.1016/j.cattod.2014.12.029

Author

Mbeleck, R. ; Mohammed, M.L. ; Ambroziak, K. et al. / Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex. In: Catalysis Today. 2015 ; Vol. 256, No. 2. pp. 287-293.

Bibtex

@article{07beebd13a0745bf9a850de6391878fc,
title = "Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex",
abstract = "A polybenzimidazole supported Mo(VI) complex (PBI.Mo) has been prepared and characterised. The catalytic activity of PBI.Mo for the epoxidation of cyclododecene and dodecene with tert-butyl hydroperoxide (TBHP) as an oxidant has been studied under different reaction conditions in a batch reactor. The stability of heterogeneous Mo(VI) catalyst was evaluated by recycling a sample in batch reaction using conditions that will form the basis of continuous process. The leaching of Mo species from PBI.Mo has been investigated by isolating any residue from reaction supernatant solutions following the removal of the heterogeneous catalyst, then using the residues as potential catalyst in epoxidation reactions. The batch epoxidation experimental data provided useful information for conducting continuous epoxidation in a reactive distillation column (RDC).",
author = "R. Mbeleck and M.L. Mohammed and K. Ambroziak and D.C. Sherrington and B. Saha",
year = "2015",
month = nov,
day = "1",
doi = "10.1016/j.cattod.2014.12.029",
language = "English",
volume = "256",
pages = "287--293",
journal = "Catalysis Today",
issn = "0920-5861",
publisher = "Elsevier",
number = "2",

}

RIS

TY - JOUR

T1 - Efficient epoxidation of cyclododecene and dodecene catalysed by polybenzimidazole supported Mo(VI) complex

AU - Mbeleck, R.

AU - Mohammed, M.L.

AU - Ambroziak, K.

AU - Sherrington, D.C.

AU - Saha, B.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - A polybenzimidazole supported Mo(VI) complex (PBI.Mo) has been prepared and characterised. The catalytic activity of PBI.Mo for the epoxidation of cyclododecene and dodecene with tert-butyl hydroperoxide (TBHP) as an oxidant has been studied under different reaction conditions in a batch reactor. The stability of heterogeneous Mo(VI) catalyst was evaluated by recycling a sample in batch reaction using conditions that will form the basis of continuous process. The leaching of Mo species from PBI.Mo has been investigated by isolating any residue from reaction supernatant solutions following the removal of the heterogeneous catalyst, then using the residues as potential catalyst in epoxidation reactions. The batch epoxidation experimental data provided useful information for conducting continuous epoxidation in a reactive distillation column (RDC).

AB - A polybenzimidazole supported Mo(VI) complex (PBI.Mo) has been prepared and characterised. The catalytic activity of PBI.Mo for the epoxidation of cyclododecene and dodecene with tert-butyl hydroperoxide (TBHP) as an oxidant has been studied under different reaction conditions in a batch reactor. The stability of heterogeneous Mo(VI) catalyst was evaluated by recycling a sample in batch reaction using conditions that will form the basis of continuous process. The leaching of Mo species from PBI.Mo has been investigated by isolating any residue from reaction supernatant solutions following the removal of the heterogeneous catalyst, then using the residues as potential catalyst in epoxidation reactions. The batch epoxidation experimental data provided useful information for conducting continuous epoxidation in a reactive distillation column (RDC).

U2 - 10.1016/j.cattod.2014.12.029

DO - 10.1016/j.cattod.2014.12.029

M3 - Journal article

VL - 256

SP - 287

EP - 293

JO - Catalysis Today

JF - Catalysis Today

SN - 0920-5861

IS - 2

ER -