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Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines. / Griffiths, Kieran; Kumar, Prashant; Mattock, James D. et al.
In: Inorganic Chemistry, Vol. 55, No. 14, 18.07.2016, p. 6988-6994.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Griffiths, K, Kumar, P, Mattock, JD, Abdul-Sada, A, Pitak, MB, Coles, SJ, Navarro, O, Vargas, A & Kostakis, GE 2016, 'Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines', Inorganic Chemistry, vol. 55, no. 14, pp. 6988-6994. https://doi.org/10.1021/acs.inorgchem.6b00720

APA

Griffiths, K., Kumar, P., Mattock, J. D., Abdul-Sada, A., Pitak, M. B., Coles, S. J., Navarro, O., Vargas, A., & Kostakis, G. E. (2016). Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines. Inorganic Chemistry, 55(14), 6988-6994. https://doi.org/10.1021/acs.inorgchem.6b00720

Vancouver

Griffiths K, Kumar P, Mattock JD, Abdul-Sada A, Pitak MB, Coles SJ et al. Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines. Inorganic Chemistry. 2016 Jul 18;55(14):6988-6994. doi: 10.1021/acs.inorgchem.6b00720

Author

Griffiths, Kieran ; Kumar, Prashant ; Mattock, James D. et al. / Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines. In: Inorganic Chemistry. 2016 ; Vol. 55, No. 14. pp. 6988-6994.

Bibtex

@article{edfc82a8c1a64ea282ea3237b609a080,
title = "Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines",
abstract = "A series of heterometallic coordination clusters (CCs) [NiII2LnIII2(L1)4Cl2(CH3CN)2] 2CH3CN [Ln = Y (1Y), Sm (1Sm), Eu (1Eu), Gd (1Gd), or Tb (1Tb)] were synthesized by the reaction of (E)-2-(2-hydroxy-3-methoxybenzylidene-amino)phenol) (H2L1) with NiCl2·6(H2O) and LnCl3·x(H2O) in the presence of Et3N at room temperature. These air-stable CCs can be obtained in very high yields from commercially available materials and are efficient catalysts for the room-temperature domino ring-opening electrocyclization synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. Structural modification of the catalyst to achieve immobilization or photosensitivity is possible without deterioration in catalytic activity.",
author = "Kieran Griffiths and Prashant Kumar and Mattock, {James D.} and Alaa Abdul-Sada and Pitak, {Mateusz B.} and Coles, {Simon J.} and Oscar Navarro and Alfredo Vargas and Kostakis, {George E.}",
year = "2016",
month = jul,
day = "18",
doi = "10.1021/acs.inorgchem.6b00720",
language = "English",
volume = "55",
pages = "6988--6994",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "14",

}

RIS

TY - JOUR

T1 - Efficient NiII2LnIII2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines

AU - Griffiths, Kieran

AU - Kumar, Prashant

AU - Mattock, James D.

AU - Abdul-Sada, Alaa

AU - Pitak, Mateusz B.

AU - Coles, Simon J.

AU - Navarro, Oscar

AU - Vargas, Alfredo

AU - Kostakis, George E.

PY - 2016/7/18

Y1 - 2016/7/18

N2 - A series of heterometallic coordination clusters (CCs) [NiII2LnIII2(L1)4Cl2(CH3CN)2] 2CH3CN [Ln = Y (1Y), Sm (1Sm), Eu (1Eu), Gd (1Gd), or Tb (1Tb)] were synthesized by the reaction of (E)-2-(2-hydroxy-3-methoxybenzylidene-amino)phenol) (H2L1) with NiCl2·6(H2O) and LnCl3·x(H2O) in the presence of Et3N at room temperature. These air-stable CCs can be obtained in very high yields from commercially available materials and are efficient catalysts for the room-temperature domino ring-opening electrocyclization synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. Structural modification of the catalyst to achieve immobilization or photosensitivity is possible without deterioration in catalytic activity.

AB - A series of heterometallic coordination clusters (CCs) [NiII2LnIII2(L1)4Cl2(CH3CN)2] 2CH3CN [Ln = Y (1Y), Sm (1Sm), Eu (1Eu), Gd (1Gd), or Tb (1Tb)] were synthesized by the reaction of (E)-2-(2-hydroxy-3-methoxybenzylidene-amino)phenol) (H2L1) with NiCl2·6(H2O) and LnCl3·x(H2O) in the presence of Et3N at room temperature. These air-stable CCs can be obtained in very high yields from commercially available materials and are efficient catalysts for the room-temperature domino ring-opening electrocyclization synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. Structural modification of the catalyst to achieve immobilization or photosensitivity is possible without deterioration in catalytic activity.

U2 - 10.1021/acs.inorgchem.6b00720

DO - 10.1021/acs.inorgchem.6b00720

M3 - Journal article

AN - SCOPUS:84978758078

VL - 55

SP - 6988

EP - 6994

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 14

ER -