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Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3

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Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3. / Li, Maoshuai; Wang, Xiaodong; Perret, Noemie et al.
In: Catalysis Communications, Vol. 46, 2014, p. 187-191.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Li, M, Wang, X, Perret, N & Keane, MA 2014, 'Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3', Catalysis Communications, vol. 46, pp. 187-191. https://doi.org/10.1016/j.catcom.2013.12.024

APA

Li, M., Wang, X., Perret, N., & Keane, M. A. (2014). Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3. Catalysis Communications, 46, 187-191. https://doi.org/10.1016/j.catcom.2013.12.024

Vancouver

Li M, Wang X, Perret N, Keane MA. Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3. Catalysis Communications. 2014;46:187-191. doi: 10.1016/j.catcom.2013.12.024

Author

Li, Maoshuai ; Wang, Xiaodong ; Perret, Noemie et al. / Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3. In: Catalysis Communications. 2014 ; Vol. 46. pp. 187-191.

Bibtex

@article{b1a85aa44c014a469a0bab5ef0863482,
title = "Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3",
abstract = "Exclusive hydrogenation of benzaldehyde to benzyl alcohol in gas phase continuous operation (393–413 K, 1 atm) was achieved over Au/Al2O3, Au/TiO2 and Au/ZrO2. Synthesis of Au/Al2O3 by deposition–precipitation generated a narrower distribution (2–8 nm) of smaller (mean = 4.3 nm) Au particles relative to impregnation (1–21 nm, mean = 7.9 nm) with increased H2 uptake under reaction conditions and higher benzaldehyde turnover. Switching reactant carrier from ethanol to water resulted in a significant enhancement of selective hydrogenation rate over Au/Al2O3 with 100% benzyl alcohol yield, attributed to increased available reactive hydrogen. This response extends to reaction over Au/TiO2 and Au/ZrO2.",
author = "Maoshuai Li and Xiaodong Wang and Noemie Perret and Keane, {Mark A.}",
year = "2014",
doi = "10.1016/j.catcom.2013.12.024",
language = "English",
volume = "46",
pages = "187--191",
journal = "Catalysis Communications",
issn = "1566-7367",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Enhanced production of benzyl alcohol in the gas phase continuous hydrogenation of benzaldehyde over Au/Al2O3

AU - Li, Maoshuai

AU - Wang, Xiaodong

AU - Perret, Noemie

AU - Keane, Mark A.

PY - 2014

Y1 - 2014

N2 - Exclusive hydrogenation of benzaldehyde to benzyl alcohol in gas phase continuous operation (393–413 K, 1 atm) was achieved over Au/Al2O3, Au/TiO2 and Au/ZrO2. Synthesis of Au/Al2O3 by deposition–precipitation generated a narrower distribution (2–8 nm) of smaller (mean = 4.3 nm) Au particles relative to impregnation (1–21 nm, mean = 7.9 nm) with increased H2 uptake under reaction conditions and higher benzaldehyde turnover. Switching reactant carrier from ethanol to water resulted in a significant enhancement of selective hydrogenation rate over Au/Al2O3 with 100% benzyl alcohol yield, attributed to increased available reactive hydrogen. This response extends to reaction over Au/TiO2 and Au/ZrO2.

AB - Exclusive hydrogenation of benzaldehyde to benzyl alcohol in gas phase continuous operation (393–413 K, 1 atm) was achieved over Au/Al2O3, Au/TiO2 and Au/ZrO2. Synthesis of Au/Al2O3 by deposition–precipitation generated a narrower distribution (2–8 nm) of smaller (mean = 4.3 nm) Au particles relative to impregnation (1–21 nm, mean = 7.9 nm) with increased H2 uptake under reaction conditions and higher benzaldehyde turnover. Switching reactant carrier from ethanol to water resulted in a significant enhancement of selective hydrogenation rate over Au/Al2O3 with 100% benzyl alcohol yield, attributed to increased available reactive hydrogen. This response extends to reaction over Au/TiO2 and Au/ZrO2.

U2 - 10.1016/j.catcom.2013.12.024

DO - 10.1016/j.catcom.2013.12.024

M3 - Journal article

VL - 46

SP - 187

EP - 191

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -