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Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications. / Howes, A.P.; Anupõld, T.; Lemaitre, V. et al.
In: Chemical Physics Letters, Vol. 421, No. 1-3, 03.04.2006, p. 42-46.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Howes, AP, Anupõld, T, Lemaitre, V, Kukol, A, Watts, A, Samoson, A, Smith, ME & Dupree, R 2006, 'Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications', Chemical Physics Letters, vol. 421, no. 1-3, pp. 42-46. https://doi.org/10.1016/j.cplett.2006.01.061

APA

Howes, A. P., Anupõld, T., Lemaitre, V., Kukol, A., Watts, A., Samoson, A., Smith, M. E., & Dupree, R. (2006). Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications. Chemical Physics Letters, 421(1-3), 42-46. https://doi.org/10.1016/j.cplett.2006.01.061

Vancouver

Howes AP, Anupõld T, Lemaitre V, Kukol A, Watts A, Samoson A et al. Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications. Chemical Physics Letters. 2006 Apr 3;421(1-3):42-46. doi: 10.1016/j.cplett.2006.01.061

Author

Howes, A.P. ; Anupõld, T. ; Lemaitre, V. et al. / Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications. In: Chemical Physics Letters. 2006 ; Vol. 421, No. 1-3. pp. 42-46.

Bibtex

@article{e10cbdf781b1413e9883b463e8483a9a,
title = "Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications",
abstract = "17O solid-state NMR is a highly sensitive probe of structural detail of organic solids but improvements in sensitivity and resolution are crucial for it to be applied to larger biological molecules. Here it is shown that high resolution (∼1 ppm) and significant signal enhancement can be achieved by combining 1H decoupled double rotation (DOR), which narrows the lines by a factor of ∼100 compared to conventional magic angle spinning, and manipulation of the satellite transition populations to transfer magnetisation to the central transition, which produces a signal enhancement of ∼2. {\textcopyright} 2006 Elsevier B.V. All rights reserved.",
keywords = "Centralized signal control, Magnetization, Modulation, Molecular orientation, Sensitivity analysis, Angle spinning, Biomolecular applications, Decoupled double rotation (DOR), Satellite transition populations, Nuclear magnetic resonance",
author = "A.P. Howes and T. Anup{\~o}ld and V. Lemaitre and A. Kukol and A. Watts and A. Samoson and M.E. Smith and R. Dupree",
year = "2006",
month = apr,
day = "3",
doi = "10.1016/j.cplett.2006.01.061",
language = "English",
volume = "421",
pages = "42--46",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - Enhancing resolution and sensitivity of 17O solid-state NMR through combining double rotation, 1H decoupling and satellite modulation for biomolecular applications

AU - Howes, A.P.

AU - Anupõld, T.

AU - Lemaitre, V.

AU - Kukol, A.

AU - Watts, A.

AU - Samoson, A.

AU - Smith, M.E.

AU - Dupree, R.

PY - 2006/4/3

Y1 - 2006/4/3

N2 - 17O solid-state NMR is a highly sensitive probe of structural detail of organic solids but improvements in sensitivity and resolution are crucial for it to be applied to larger biological molecules. Here it is shown that high resolution (∼1 ppm) and significant signal enhancement can be achieved by combining 1H decoupled double rotation (DOR), which narrows the lines by a factor of ∼100 compared to conventional magic angle spinning, and manipulation of the satellite transition populations to transfer magnetisation to the central transition, which produces a signal enhancement of ∼2. © 2006 Elsevier B.V. All rights reserved.

AB - 17O solid-state NMR is a highly sensitive probe of structural detail of organic solids but improvements in sensitivity and resolution are crucial for it to be applied to larger biological molecules. Here it is shown that high resolution (∼1 ppm) and significant signal enhancement can be achieved by combining 1H decoupled double rotation (DOR), which narrows the lines by a factor of ∼100 compared to conventional magic angle spinning, and manipulation of the satellite transition populations to transfer magnetisation to the central transition, which produces a signal enhancement of ∼2. © 2006 Elsevier B.V. All rights reserved.

KW - Centralized signal control

KW - Magnetization

KW - Modulation

KW - Molecular orientation

KW - Sensitivity analysis

KW - Angle spinning

KW - Biomolecular applications

KW - Decoupled double rotation (DOR)

KW - Satellite transition populations

KW - Nuclear magnetic resonance

U2 - 10.1016/j.cplett.2006.01.061

DO - 10.1016/j.cplett.2006.01.061

M3 - Journal article

VL - 421

SP - 42

EP - 46

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

ER -