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Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect. / Al-Yasari, Ahmed; Spence, Philip; El Moll, Hani et al.
In: Dalton Transactions, Vol. 47, No. 31, 21.08.2018, p. 10415-10419.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Al-Yasari, A, Spence, P, El Moll, H, van Steerteghem, N, Horton, PN, Brunschwig, BS, Clays, K & Fielden, J 2018, 'Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect', Dalton Transactions, vol. 47, no. 31, pp. 10415-10419. https://doi.org/10.1039/C8DT01491D

APA

Al-Yasari, A., Spence, P., El Moll, H., van Steerteghem, N., Horton, P. N., Brunschwig, B. S., Clays, K., & Fielden, J. (2018). Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect. Dalton Transactions, 47(31), 10415-10419. https://doi.org/10.1039/C8DT01491D

Vancouver

Al-Yasari A, Spence P, El Moll H, van Steerteghem N, Horton PN, Brunschwig BS et al. Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect. Dalton Transactions. 2018 Aug 21;47(31):10415-10419. doi: 10.1039/C8DT01491D

Author

Al-Yasari, Ahmed ; Spence, Philip ; El Moll, Hani et al. / Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect. In: Dalton Transactions. 2018 ; Vol. 47, No. 31. pp. 10415-10419.

Bibtex

@article{187ebc4427354b409c902867a5535a2b,
title = "Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect",
abstract = "A new aryl-imido polyoxometalate non-linear optical chromophore (POMophore) with a diphenylamino donor group attains the highest βzzz, 0 value (196 × 10−30 esu by Hyper-Rayleigh Scattering, HRS), and best transparency/non-linearity trade off yet for such materials. Stark spectroscopic and DFT investigation of this compound, plus NMe2 and carbazole analogues, show that its high performance results from a combination of strongly dipolar electronic transitions, and strong electronic communication across the π-system.",
author = "Ahmed Al-Yasari and Philip Spence and {El Moll}, Hani and {van Steerteghem}, Nick and Horton, {Peter N.} and Brunschwig, {Bruce S.} and Koen Clays and John Fielden",
year = "2018",
month = aug,
day = "21",
doi = "10.1039/C8DT01491D",
language = "English",
volume = "47",
pages = "10415--10419",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "31",

}

RIS

TY - JOUR

T1 - Fine-tuning polyoxometalate non-linear optical chromophores: a molecular electronic “Goldilocks” effect

AU - Al-Yasari, Ahmed

AU - Spence, Philip

AU - El Moll, Hani

AU - van Steerteghem, Nick

AU - Horton, Peter N.

AU - Brunschwig, Bruce S.

AU - Clays, Koen

AU - Fielden, John

PY - 2018/8/21

Y1 - 2018/8/21

N2 - A new aryl-imido polyoxometalate non-linear optical chromophore (POMophore) with a diphenylamino donor group attains the highest βzzz, 0 value (196 × 10−30 esu by Hyper-Rayleigh Scattering, HRS), and best transparency/non-linearity trade off yet for such materials. Stark spectroscopic and DFT investigation of this compound, plus NMe2 and carbazole analogues, show that its high performance results from a combination of strongly dipolar electronic transitions, and strong electronic communication across the π-system.

AB - A new aryl-imido polyoxometalate non-linear optical chromophore (POMophore) with a diphenylamino donor group attains the highest βzzz, 0 value (196 × 10−30 esu by Hyper-Rayleigh Scattering, HRS), and best transparency/non-linearity trade off yet for such materials. Stark spectroscopic and DFT investigation of this compound, plus NMe2 and carbazole analogues, show that its high performance results from a combination of strongly dipolar electronic transitions, and strong electronic communication across the π-system.

U2 - 10.1039/C8DT01491D

DO - 10.1039/C8DT01491D

M3 - Journal article

VL - 47

SP - 10415

EP - 10419

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 31

ER -