Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands
AU - Buchard, Antoine
AU - Auffrant, Audrey
AU - Ricard, Louis
AU - Le Goff, Xavier F.
AU - Platel, Rachel H.
AU - Williams, Charlotte K.
AU - Le Floch, Pascal
PY - 2009
Y1 - 2009
N2 - Serendipitous deprotonation of bis(iminophosphoranyl) methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.
AB - Serendipitous deprotonation of bis(iminophosphoranyl) methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.
KW - METAL
KW - SEQUENTIAL HYDROAMINATION/HYDROSILYLATION
KW - CATALYSIS
KW - MOLECULAR-STRUCTURE
KW - CARBON MULTIPLE BOND
KW - CRYSTAL-STRUCTURES
KW - COORDINATION
KW - REACTIVITY
KW - HYDROSILYLATION
KW - YTTRIUM
U2 - 10.1039/b918971h
DO - 10.1039/b918971h
M3 - Journal article
SP - 10219
EP - 10222
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 46
ER -