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Fluorine-based Zn salan complexes

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Fluorine-based Zn salan complexes. / Essien, Nsikak B.; Galvácsi, Antal; Kállay, Csilla et al.
In: Dalton Transactions, Vol. 52, No. 13, 07.04.2023, p. 4044-4057.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Essien, NB, Galvácsi, A, Kállay, C, Al-Hilaly, Y, González-Méndez, R, Akien, GR, Tizzard, GJ, Coles, SJ, Besora, M & Kostakis, GE 2023, 'Fluorine-based Zn salan complexes', Dalton Transactions, vol. 52, no. 13, pp. 4044-4057. https://doi.org/10.1039/d2dt04082d

APA

Essien, N. B., Galvácsi, A., Kállay, C., Al-Hilaly, Y., González-Méndez, R., Akien, G. R., Tizzard, G. J., Coles, S. J., Besora, M., & Kostakis, G. E. (2023). Fluorine-based Zn salan complexes. Dalton Transactions, 52(13), 4044-4057. https://doi.org/10.1039/d2dt04082d

Vancouver

Essien NB, Galvácsi A, Kállay C, Al-Hilaly Y, González-Méndez R, Akien GR et al. Fluorine-based Zn salan complexes. Dalton Transactions. 2023 Apr 7;52(13):4044-4057. Epub 2023 Feb 24. doi: 10.1039/d2dt04082d

Author

Essien, Nsikak B. ; Galvácsi, Antal ; Kállay, Csilla et al. / Fluorine-based Zn salan complexes. In: Dalton Transactions. 2023 ; Vol. 52, No. 13. pp. 4044-4057.

Bibtex

@article{b2fa636783c54cfda987f3aa7818da10,
title = "Fluorine-based Zn salan complexes",
abstract = "We synthesised and characterised the racemic and chiral versions of two Zn salan fluorine-based complexes from commercially available materials. The complexes are susceptible to absorbing H2O from the atmosphere. In solution (DMSO–H2O) and at the millimolar level, experimental and theoretical studies identify that these complexes exist in a dimeric-monomeric equilibrium. We also investigated their ability to sense amines via19F NMR. In CDCl3 or d6-DMSO, strongly coordinating molecules (H2O or DMSO) are the limiting factor in using these easy-to-make complexes as chemosensory platforms since their exchange with analytes requires an extreme excess of the latter.",
author = "Essien, {Nsikak B.} and Antal Galv{\'a}csi and Csilla K{\'a}llay and Youssra Al-Hilaly and Ram{\'o}n Gonz{\'a}lez-M{\'e}ndez and Akien, {Geoffrey R.} and Tizzard, {Graham J.} and Coles, {Simon J.} and Maria Besora and Kostakis, {George E.}",
year = "2023",
month = apr,
day = "7",
doi = "10.1039/d2dt04082d",
language = "English",
volume = "52",
pages = "4044--4057",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "13",

}

RIS

TY - JOUR

T1 - Fluorine-based Zn salan complexes

AU - Essien, Nsikak B.

AU - Galvácsi, Antal

AU - Kállay, Csilla

AU - Al-Hilaly, Youssra

AU - González-Méndez, Ramón

AU - Akien, Geoffrey R.

AU - Tizzard, Graham J.

AU - Coles, Simon J.

AU - Besora, Maria

AU - Kostakis, George E.

PY - 2023/4/7

Y1 - 2023/4/7

N2 - We synthesised and characterised the racemic and chiral versions of two Zn salan fluorine-based complexes from commercially available materials. The complexes are susceptible to absorbing H2O from the atmosphere. In solution (DMSO–H2O) and at the millimolar level, experimental and theoretical studies identify that these complexes exist in a dimeric-monomeric equilibrium. We also investigated their ability to sense amines via19F NMR. In CDCl3 or d6-DMSO, strongly coordinating molecules (H2O or DMSO) are the limiting factor in using these easy-to-make complexes as chemosensory platforms since their exchange with analytes requires an extreme excess of the latter.

AB - We synthesised and characterised the racemic and chiral versions of two Zn salan fluorine-based complexes from commercially available materials. The complexes are susceptible to absorbing H2O from the atmosphere. In solution (DMSO–H2O) and at the millimolar level, experimental and theoretical studies identify that these complexes exist in a dimeric-monomeric equilibrium. We also investigated their ability to sense amines via19F NMR. In CDCl3 or d6-DMSO, strongly coordinating molecules (H2O or DMSO) are the limiting factor in using these easy-to-make complexes as chemosensory platforms since their exchange with analytes requires an extreme excess of the latter.

U2 - 10.1039/d2dt04082d

DO - 10.1039/d2dt04082d

M3 - Journal article

VL - 52

SP - 4044

EP - 4057

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 13

ER -