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Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects. / Griffiths, Kieran; Mayans, Julia; Shipman, Michael A. et al.
In: Crystal Growth and Design, Vol. 17, No. 4, 05.04.2017, p. 1524-1538.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Griffiths, K, Mayans, J, Shipman, MA, Tizzard, GJ, Coles, SJ, Blight, BA, Escuer, A & Kostakis, GE 2017, 'Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects', Crystal Growth and Design, vol. 17, no. 4, pp. 1524-1538. https://doi.org/10.1021/acs.cgd.6b01401

APA

Griffiths, K., Mayans, J., Shipman, M. A., Tizzard, G. J., Coles, S. J., Blight, B. A., Escuer, A., & Kostakis, G. E. (2017). Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects. Crystal Growth and Design, 17(4), 1524-1538. https://doi.org/10.1021/acs.cgd.6b01401

Vancouver

Griffiths K, Mayans J, Shipman MA, Tizzard GJ, Coles SJ, Blight BA et al. Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects. Crystal Growth and Design. 2017 Apr 5;17(4):1524-1538. doi: 10.1021/acs.cgd.6b01401

Author

Griffiths, Kieran ; Mayans, Julia ; Shipman, Michael A. et al. / Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects. In: Crystal Growth and Design. 2017 ; Vol. 17, No. 4. pp. 1524-1538.

Bibtex

@article{5558880741034d2fb2f3feb66465855c,
title = "Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects",
abstract = "The employment of three structurally related Schiff bases H2L1, H2L2, and H3L3 with zinc and lanthanide salts under various reaction conditions, gave four families of compounds formulated as [ZnII2LnIII2(L1)4(EtOH)6][ClO4]2 (1-3), [ZnII5Ln(OH)(L1)6(H2O)] (4-6), [ZnII4LnIII2(OH)2(L2)4 (OAc)2(NO3)2(DMF)3]·DMF (7-9), and [ZnII2LnIII2(L3)2(NO3)2(CO3)2(CH3OH)2] (10-12) with robust and novel topologies. Synthetic aspects are discussed. A comprehensive topological analysis of all reported ZnII/LnIII CCs with a core nuclearity of four and above is presented and identifies that families (4-6) and (7-9) are the first examples of the 2,3,4M6-1 motif in ZnII/LnIII chemistry. Magnetic studies are presented for the DyIII analogues (1, 7, and 10) are presented, 7 demonstrates field-induced slow relaxation of the magnetization. Fluorescence studies are also discussed.",
author = "Kieran Griffiths and Julia Mayans and Shipman, {Michael A.} and Tizzard, {Graham J.} and Coles, {Simon J.} and Blight, {Barry A.} and Albert Escuer and Kostakis, {George E.}",
year = "2017",
month = apr,
day = "5",
doi = "10.1021/acs.cgd.6b01401",
language = "English",
volume = "17",
pages = "1524--1538",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Four New Families of Polynuclear Zn-Ln Coordination Clusters. Synthetic, Topological, Magnetic, and Luminescent Aspects

AU - Griffiths, Kieran

AU - Mayans, Julia

AU - Shipman, Michael A.

AU - Tizzard, Graham J.

AU - Coles, Simon J.

AU - Blight, Barry A.

AU - Escuer, Albert

AU - Kostakis, George E.

PY - 2017/4/5

Y1 - 2017/4/5

N2 - The employment of three structurally related Schiff bases H2L1, H2L2, and H3L3 with zinc and lanthanide salts under various reaction conditions, gave four families of compounds formulated as [ZnII2LnIII2(L1)4(EtOH)6][ClO4]2 (1-3), [ZnII5Ln(OH)(L1)6(H2O)] (4-6), [ZnII4LnIII2(OH)2(L2)4 (OAc)2(NO3)2(DMF)3]·DMF (7-9), and [ZnII2LnIII2(L3)2(NO3)2(CO3)2(CH3OH)2] (10-12) with robust and novel topologies. Synthetic aspects are discussed. A comprehensive topological analysis of all reported ZnII/LnIII CCs with a core nuclearity of four and above is presented and identifies that families (4-6) and (7-9) are the first examples of the 2,3,4M6-1 motif in ZnII/LnIII chemistry. Magnetic studies are presented for the DyIII analogues (1, 7, and 10) are presented, 7 demonstrates field-induced slow relaxation of the magnetization. Fluorescence studies are also discussed.

AB - The employment of three structurally related Schiff bases H2L1, H2L2, and H3L3 with zinc and lanthanide salts under various reaction conditions, gave four families of compounds formulated as [ZnII2LnIII2(L1)4(EtOH)6][ClO4]2 (1-3), [ZnII5Ln(OH)(L1)6(H2O)] (4-6), [ZnII4LnIII2(OH)2(L2)4 (OAc)2(NO3)2(DMF)3]·DMF (7-9), and [ZnII2LnIII2(L3)2(NO3)2(CO3)2(CH3OH)2] (10-12) with robust and novel topologies. Synthetic aspects are discussed. A comprehensive topological analysis of all reported ZnII/LnIII CCs with a core nuclearity of four and above is presented and identifies that families (4-6) and (7-9) are the first examples of the 2,3,4M6-1 motif in ZnII/LnIII chemistry. Magnetic studies are presented for the DyIII analogues (1, 7, and 10) are presented, 7 demonstrates field-induced slow relaxation of the magnetization. Fluorescence studies are also discussed.

U2 - 10.1021/acs.cgd.6b01401

DO - 10.1021/acs.cgd.6b01401

M3 - Journal article

AN - SCOPUS:85017117791

VL - 17

SP - 1524

EP - 1538

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 4

ER -