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FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia.

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FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia. / Akyüz, Sevim; Akyüz, Tanil; Davies, J. Eric D.
In: Vibrational Spectroscopy, Vol. 22, No. 1-2, 02.2000, p. 11-17.

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Akyüz S, Akyüz T, Davies JED. FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia. Vibrational Spectroscopy. 2000 Feb;22(1-2):11-17. doi: 10.1016/S0924-2031(99)00058-2

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Akyüz, Sevim ; Akyüz, Tanil ; Davies, J. Eric D. / FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia. In: Vibrational Spectroscopy. 2000 ; Vol. 22, No. 1-2. pp. 11-17.

Bibtex

@article{9c33cdbf005149dd8489a987aa7b30b5,
title = "FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia.",
abstract = "The sorption of 2,2′-biquinoline onto natural and ion-exchanged montmorillonite (Fe-, Co- or Cu-montmorillonite) and saponite from Anatolia have been investigated using FT-IR and FT-Raman Spectrometry. The intercalation of 2,2′-biquinoline within natural and ion-exchanged montmorillonite and saponite has been shown by X-ray diffraction to increase the interlayer spacing. The difference of basal spacing of air-dried clays and biquinoline treated ones shows monolayer arrangement. Raman spectroscopy was particularly useful for investigation of clay-organic interaction. Vibrational spectroscopy indicates that intercalated 2,2′-biquinoline molecules are coordinated to exchangeable cations (directly and indirectly through water bridges) and/or Lewis acid sites or as bidentate ligand.",
keywords = "FT-IR, FT-Raman, Clay, Montmorillonite, Saponite, Intercalation, Biquinoline",
author = "Sevim Aky{\"u}z and Tanil Aky{\"u}z and Davies, {J. Eric D.}",
year = "2000",
month = feb,
doi = "10.1016/S0924-2031(99)00058-2",
language = "English",
volume = "22",
pages = "11--17",
journal = "Vibrational Spectroscopy",
issn = "0924-2031",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia.

AU - Akyüz, Sevim

AU - Akyüz, Tanil

AU - Davies, J. Eric D.

PY - 2000/2

Y1 - 2000/2

N2 - The sorption of 2,2′-biquinoline onto natural and ion-exchanged montmorillonite (Fe-, Co- or Cu-montmorillonite) and saponite from Anatolia have been investigated using FT-IR and FT-Raman Spectrometry. The intercalation of 2,2′-biquinoline within natural and ion-exchanged montmorillonite and saponite has been shown by X-ray diffraction to increase the interlayer spacing. The difference of basal spacing of air-dried clays and biquinoline treated ones shows monolayer arrangement. Raman spectroscopy was particularly useful for investigation of clay-organic interaction. Vibrational spectroscopy indicates that intercalated 2,2′-biquinoline molecules are coordinated to exchangeable cations (directly and indirectly through water bridges) and/or Lewis acid sites or as bidentate ligand.

AB - The sorption of 2,2′-biquinoline onto natural and ion-exchanged montmorillonite (Fe-, Co- or Cu-montmorillonite) and saponite from Anatolia have been investigated using FT-IR and FT-Raman Spectrometry. The intercalation of 2,2′-biquinoline within natural and ion-exchanged montmorillonite and saponite has been shown by X-ray diffraction to increase the interlayer spacing. The difference of basal spacing of air-dried clays and biquinoline treated ones shows monolayer arrangement. Raman spectroscopy was particularly useful for investigation of clay-organic interaction. Vibrational spectroscopy indicates that intercalated 2,2′-biquinoline molecules are coordinated to exchangeable cations (directly and indirectly through water bridges) and/or Lewis acid sites or as bidentate ligand.

KW - FT-IR

KW - FT-Raman

KW - Clay

KW - Montmorillonite

KW - Saponite

KW - Intercalation

KW - Biquinoline

U2 - 10.1016/S0924-2031(99)00058-2

DO - 10.1016/S0924-2031(99)00058-2

M3 - Journal article

VL - 22

SP - 11

EP - 17

JO - Vibrational Spectroscopy

JF - Vibrational Spectroscopy

SN - 0924-2031

IS - 1-2

ER -