FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS. / Bevington, J. C.; Huckerby, T. N.; Hunt, B. J. et al.
In: Journal of Macromolecular Science Part A Pure and Applied Chemistry, Vol. 38, No. 10, 2001, p. 981-990.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Bevington, JC, Huckerby, TN, Hunt, BJ & Jenkins, AD 2001, 'FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS.', Journal of Macromolecular Science Part A Pure and Applied Chemistry, vol. 38, no. 10, pp. 981-990. https://doi.org/10.1081/MA-100105960

APA

Bevington, J. C., Huckerby, T. N., Hunt, B. J., & Jenkins, A. D. (2001). FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS. Journal of Macromolecular Science Part A Pure and Applied Chemistry, 38(10), 981-990. https://doi.org/10.1081/MA-100105960

Vancouver

Bevington JC, Huckerby TN, Hunt BJ, Jenkins AD. FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS. Journal of Macromolecular Science Part A Pure and Applied Chemistry. 2001;38(10):981-990. doi: 10.1081/MA-100105960

Author

Bevington, J. C. ; Huckerby, T. N. ; Hunt, B. J. et al. / FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS. In: Journal of Macromolecular Science Part A Pure and Applied Chemistry. 2001 ; Vol. 38, No. 10. pp. 981-990.

Bibtex

@article{fe636bbfe40342d6a4a4ac09bd9eea85,

title = "FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS.",

abstract = "Allyl glycidyl ether (AGE), allyl 1,1,2,3,3,3-hexafluoropropyl ether (AFE), allyl 2-naphthyl ether (ANE), 2-vinyl-1,3-dioxolane (2VD) and allyl alcohol (AA) have been examined as transfer agents in the radical polymerization of methyl methacrylate (MMA) at 60°C; the transfer constants are 1.1 10-3, 0.1 10-3, 0.2 10-3, 1.1 10-3 and 0.6 10-3, respectively. AFE and AA barely affect the rate of polymerization: AGE, ANE, and 2VD act as weak retarders. There is no direct correlation between effectiveness as a transfer agent and the extent of retardation for these additives. For copolymerization with MMA (monomer-1), the monomer reactivity ratios r1 are 42 ± 5 and 32 ± 5 for AGE and ANE, respectively; for both cases, r2 is very close to zero; 2VD engages in copolymerization with MMA to a negligible extent. Experiments involving styrene or acrylonitrile gave results consistent with those obtained using MMA.",

keywords = "Radical polymerization, Transfer, Retardation, Allyl ethers",

author = "Bevington, {J. C.} and Huckerby, {T. N.} and Hunt, {B. J.} and Jenkins, {A. D.}",

year = "2001",

doi = "10.1081/MA-100105960",

language = "English",

volume = "38",

pages = "981--990",

journal = "Journal of Macromolecular Science Part A Pure and Applied Chemistry",

issn = "1060-1325",

publisher = "Taylor and Francis Ltd.",

number = "10",

}

RIS

TY - JOUR

T1 - FURTHER STUDY OF ALLYL ETHERS AND RELATED COMPOUNDS AS TRANSFER AGENTS IN RADICAL POLYMERIZATIONS.

AU - Bevington, J. C.

AU - Huckerby, T. N.

AU - Hunt, B. J.

AU - Jenkins, A. D.

PY - 2001

Y1 - 2001

N2 - Allyl glycidyl ether (AGE), allyl 1,1,2,3,3,3-hexafluoropropyl ether (AFE), allyl 2-naphthyl ether (ANE), 2-vinyl-1,3-dioxolane (2VD) and allyl alcohol (AA) have been examined as transfer agents in the radical polymerization of methyl methacrylate (MMA) at 60°C; the transfer constants are 1.1 10-3, 0.1 10-3, 0.2 10-3, 1.1 10-3 and 0.6 10-3, respectively. AFE and AA barely affect the rate of polymerization: AGE, ANE, and 2VD act as weak retarders. There is no direct correlation between effectiveness as a transfer agent and the extent of retardation for these additives. For copolymerization with MMA (monomer-1), the monomer reactivity ratios r1 are 42 ± 5 and 32 ± 5 for AGE and ANE, respectively; for both cases, r2 is very close to zero; 2VD engages in copolymerization with MMA to a negligible extent. Experiments involving styrene or acrylonitrile gave results consistent with those obtained using MMA.

AB - Allyl glycidyl ether (AGE), allyl 1,1,2,3,3,3-hexafluoropropyl ether (AFE), allyl 2-naphthyl ether (ANE), 2-vinyl-1,3-dioxolane (2VD) and allyl alcohol (AA) have been examined as transfer agents in the radical polymerization of methyl methacrylate (MMA) at 60°C; the transfer constants are 1.1 10-3, 0.1 10-3, 0.2 10-3, 1.1 10-3 and 0.6 10-3, respectively. AFE and AA barely affect the rate of polymerization: AGE, ANE, and 2VD act as weak retarders. There is no direct correlation between effectiveness as a transfer agent and the extent of retardation for these additives. For copolymerization with MMA (monomer-1), the monomer reactivity ratios r1 are 42 ± 5 and 32 ± 5 for AGE and ANE, respectively; for both cases, r2 is very close to zero; 2VD engages in copolymerization with MMA to a negligible extent. Experiments involving styrene or acrylonitrile gave results consistent with those obtained using MMA.

KW - Radical polymerization

KW - Transfer

KW - Retardation

KW - Allyl ethers

U2 - 10.1081/MA-100105960

DO - 10.1081/MA-100105960

M3 - Journal article

VL - 38

SP - 981

EP - 990

JO - Journal of Macromolecular Science Part A Pure and Applied Chemistry

JF - Journal of Macromolecular Science Part A Pure and Applied Chemistry

SN - 1060-1325

IS - 10

ER -

Research

Links

Text available via DOI:

Keywords