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Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses

Research output: Contribution to conference - Without ISBN/ISSN › Abstract › peer-review

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Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses. / Akien, Geoffrey; Subramaniam, Bala.
2014. Abstract from 247th ACS National Meeting, Dallas, United States.

Research output: Contribution to conference - Without ISBN/ISSN › Abstract › peer-review

Harvard

Akien, G & Subramaniam, B 2014, 'Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses', 247th ACS National Meeting, Dallas, United States, 16/03/14 - 21/03/14.

APA

Akien, G., & Subramaniam, B. (2014). Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses. Abstract from 247th ACS National Meeting, Dallas, United States.

Vancouver

Akien G, Subramaniam B. Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses. 2014. Abstract from 247th ACS National Meeting, Dallas, United States.

Author

Akien, Geoffrey ; Subramaniam, Bala. / Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses. Abstract from 247th ACS National Meeting, Dallas, United States.

Bibtex

@conference{092c67606ede4782864fbe876e9ba7fc,
title = "Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses",
abstract = "Previously, we were able to generate and spectroscopically characterize the (tertiary) oxocarbenium ions from various protected ketofuranoses and ketopyranoses, in superacidic solutions at low temperature. For such complex species, it was perhaps surprising that they were stable at all in superacidic media.We have now extended this methodology to the even more reactive secondary oxocarbenium ions obtainable from various protected 2-deoxyaldoses. Through the measurement of J-couplings, this has allowed for the first determination of the conformation of these important intermediates in solution.",
author = "Geoffrey Akien and Bala Subramaniam",
year = "2014",
month = mar,
day = "20",
language = "English",
note = "247th ACS National Meeting ; Conference date: 16-03-2014 Through 21-03-2014",

}

RIS

TY - CONF

T1 - Generation and characterization of the pyranosyl and furanosyl oxocarbenium ions from 2-deoxyaldoses

AU - Akien, Geoffrey

AU - Subramaniam, Bala

PY - 2014/3/20

Y1 - 2014/3/20

N2 - Previously, we were able to generate and spectroscopically characterize the (tertiary) oxocarbenium ions from various protected ketofuranoses and ketopyranoses, in superacidic solutions at low temperature. For such complex species, it was perhaps surprising that they were stable at all in superacidic media.We have now extended this methodology to the even more reactive secondary oxocarbenium ions obtainable from various protected 2-deoxyaldoses. Through the measurement of J-couplings, this has allowed for the first determination of the conformation of these important intermediates in solution.

AB - Previously, we were able to generate and spectroscopically characterize the (tertiary) oxocarbenium ions from various protected ketofuranoses and ketopyranoses, in superacidic solutions at low temperature. For such complex species, it was perhaps surprising that they were stable at all in superacidic media.We have now extended this methodology to the even more reactive secondary oxocarbenium ions obtainable from various protected 2-deoxyaldoses. Through the measurement of J-couplings, this has allowed for the first determination of the conformation of these important intermediates in solution.

M3 - Abstract

T2 - 247th ACS National Meeting

Y2 - 16 March 2014 through 21 March 2014

ER -