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Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study. / Waldmann, Thomas; Nenon, Christina; Hoster, Harry E. et al.
In: Physical Chemistry Chemical Physics, Vol. 13, No. 46, 27.09.2011, p. 20724-20728.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Waldmann, T, Nenon, C, Hoster, HE & Behm, RJ 2011, 'Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study', Physical Chemistry Chemical Physics, vol. 13, no. 46, pp. 20724-20728. https://doi.org/10.1039/c1cp22546d

APA

Waldmann, T., Nenon, C., Hoster, H. E., & Behm, R. J. (2011). Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study. Physical Chemistry Chemical Physics, 13(46), 20724-20728. https://doi.org/10.1039/c1cp22546d

Vancouver

Waldmann T, Nenon C, Hoster HE, Behm RJ. Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study. Physical Chemistry Chemical Physics. 2011 Sept 27;13(46):20724-20728. doi: 10.1039/c1cp22546d

Author

Waldmann, Thomas ; Nenon, Christina ; Hoster, Harry E. et al. / Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study. In: Physical Chemistry Chemical Physics. 2011 ; Vol. 13, No. 46. pp. 20724-20728.

Bibtex

@article{e7bb25f317a646df858f839d8a6cc670,
title = "Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study",
abstract = "The growth behaviour of the oligopyridine derivative 2-phenyl-4,6-bis(6-(pyridine-2-yl)-4-(pyridine-4-yl) pyridine-2-yl) pyrimidine (2,4'-BTP) on Ag(100) in the sub-monolayer regime was investigated by variable temperature scanning tunneling microscopy under ultra-high vacuum conditions. Over the entire coverage range, the molecules are adsorbed in a flat lying configuration, with preferential orientations with respect to the <110 > direction of the surface. The azimuth angles are derived using a previously introduced algorithm that fits the positions of the intramolecular N atoms geometrically to the underlying surface lattice ({"}points-to-lattice fit{"}) [H. E. Hoster et al., Langmuir 2007, 23, 11570], indicating that the orientation of the admolecules and thus of the adllayer structure with respect to the Ag(100) surface lattice is determined by the 2,40-BTP - Ag(100) interaction, while intermolecular interactions are decisive for the structure of the adlayer. The results will be compared to other adsorption systems.",
keywords = "METAL-SURFACES, ORGANIC-MOLECULES, PYROLYTIC-GRAPHITE, ADSORPTION, ASSEMBLIES, COMPLEXES, SUBSTRATE, CU(110)",
author = "Thomas Waldmann and Christina Nenon and Hoster, {Harry E.} and Behm, {R. Juergen}",
year = "2011",
month = sep,
day = "27",
doi = "10.1039/c1cp22546d",
language = "English",
volume = "13",
pages = "20724--20728",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "46",

}

RIS

TY - JOUR

T1 - Growth of an oligopyridine adlayer on Ag(100) - a scanning tunnelling microscopy study

AU - Waldmann, Thomas

AU - Nenon, Christina

AU - Hoster, Harry E.

AU - Behm, R. Juergen

PY - 2011/9/27

Y1 - 2011/9/27

N2 - The growth behaviour of the oligopyridine derivative 2-phenyl-4,6-bis(6-(pyridine-2-yl)-4-(pyridine-4-yl) pyridine-2-yl) pyrimidine (2,4'-BTP) on Ag(100) in the sub-monolayer regime was investigated by variable temperature scanning tunneling microscopy under ultra-high vacuum conditions. Over the entire coverage range, the molecules are adsorbed in a flat lying configuration, with preferential orientations with respect to the <110 > direction of the surface. The azimuth angles are derived using a previously introduced algorithm that fits the positions of the intramolecular N atoms geometrically to the underlying surface lattice ("points-to-lattice fit") [H. E. Hoster et al., Langmuir 2007, 23, 11570], indicating that the orientation of the admolecules and thus of the adllayer structure with respect to the Ag(100) surface lattice is determined by the 2,40-BTP - Ag(100) interaction, while intermolecular interactions are decisive for the structure of the adlayer. The results will be compared to other adsorption systems.

AB - The growth behaviour of the oligopyridine derivative 2-phenyl-4,6-bis(6-(pyridine-2-yl)-4-(pyridine-4-yl) pyridine-2-yl) pyrimidine (2,4'-BTP) on Ag(100) in the sub-monolayer regime was investigated by variable temperature scanning tunneling microscopy under ultra-high vacuum conditions. Over the entire coverage range, the molecules are adsorbed in a flat lying configuration, with preferential orientations with respect to the <110 > direction of the surface. The azimuth angles are derived using a previously introduced algorithm that fits the positions of the intramolecular N atoms geometrically to the underlying surface lattice ("points-to-lattice fit") [H. E. Hoster et al., Langmuir 2007, 23, 11570], indicating that the orientation of the admolecules and thus of the adllayer structure with respect to the Ag(100) surface lattice is determined by the 2,40-BTP - Ag(100) interaction, while intermolecular interactions are decisive for the structure of the adlayer. The results will be compared to other adsorption systems.

KW - METAL-SURFACES

KW - ORGANIC-MOLECULES

KW - PYROLYTIC-GRAPHITE

KW - ADSORPTION

KW - ASSEMBLIES

KW - COMPLEXES

KW - SUBSTRATE

KW - CU(110)

U2 - 10.1039/c1cp22546d

DO - 10.1039/c1cp22546d

M3 - Journal article

VL - 13

SP - 20724

EP - 20728

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 46

ER -