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Halide anion recognition by new acyclic ruthenium (II) bipyridyl-polypyridinium receptors

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<mark>Journal publication date</mark>1/10/1996
<mark>Journal</mark>Inorganica Chimica Acta
Issue number1-2 PART II
Volume251
Number of pages6
Pages (from-to)335-340
Publication StatusPublished
<mark>Original language</mark>English

Abstract

New acyclic ruthenium(II) bipyridyl-pyridinium receptor molecules have been synthesised. 1H NMR spectroscopy, and cyclic and square wave voltammetry have established these receptors complex and electrochemically sense the chloride anion. Disappointingly spectral detection of halide anions by electronic absorption and fluorescence-emission spectroscopic measurements was unsuccessful.