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Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters: Synthesis, Structures and Magnetic Properties

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters: Synthesis, Structures and Magnetic Properties. / Griffiths, Kieran; Harding, Chris; Dokorou, Vasiliki N. et al.
In: European Journal of Inorganic Chemistry, Vol. 2017, No. 33, 08.09.2017, p. 3938-3945.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Griffiths, K, Harding, C, Dokorou, VN, Loukopoulos, E, Sampani, SI, Abdul-Sada, A, Tizzard, GJ, Coles, SJ, Lorusso, G, Evangelisti, M, Escuer, A & Kostakis, GE 2017, 'Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters: Synthesis, Structures and Magnetic Properties', European Journal of Inorganic Chemistry, vol. 2017, no. 33, pp. 3938-3945. https://doi.org/10.1002/ejic.201700728

APA

Griffiths, K., Harding, C., Dokorou, V. N., Loukopoulos, E., Sampani, S. I., Abdul-Sada, A., Tizzard, G. J., Coles, S. J., Lorusso, G., Evangelisti, M., Escuer, A., & Kostakis, G. E. (2017). Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters: Synthesis, Structures and Magnetic Properties. European Journal of Inorganic Chemistry, 2017(33), 3938-3945. https://doi.org/10.1002/ejic.201700728

Vancouver

Griffiths K, Harding C, Dokorou VN, Loukopoulos E, Sampani SI, Abdul-Sada A et al. Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters: Synthesis, Structures and Magnetic Properties. European Journal of Inorganic Chemistry. 2017 Sept 8;2017(33):3938-3945. doi: 10.1002/ejic.201700728

Author

Griffiths, Kieran ; Harding, Chris ; Dokorou, Vasiliki N. et al. / Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters : Synthesis, Structures and Magnetic Properties. In: European Journal of Inorganic Chemistry. 2017 ; Vol. 2017, No. 33. pp. 3938-3945.

Bibtex

@article{b40ed3d7f5fe449c8e04b7375b771eb2,
title = "Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters: Synthesis, Structures and Magnetic Properties",
abstract = "The synthesis, characterization, crystal structures and magnetic properties of isoskeletal heptanuclear disk-like MII 3LnIII 4 coordination clusters with the general formula [CoII 3LnIII 4(µ3-OH)6L6(CF3SO3)][(CF3SO3)5] where Ln = Gd (2), Y (3) and [NiII 3LnIII 4(µ3-OH)6L6(CF3SO3)][(CF3SO3)5] where Ln = Dy (4), Gd (5), Y (6) are presented. All the compounds are stable in solution as confirmed by ESI-MS. Magnetic studies were performed for compounds 2, 4, 5 and 6 and indicate ferromagnetic coupling while the magnetocaloric properties of 5 are characterized by ΔSm = –15.4 J kg–1 K–1 at T = 5.0 K and ΔTad = 5.9 K at T = 2.3 K, for µ0ΔH = 7 T.",
keywords = "Cluster compounds, Disk-like, Magnetic properties, Schiff bases, Topology",
author = "Kieran Griffiths and Chris Harding and Dokorou, {Vasiliki N.} and Edward Loukopoulos and Sampani, {Stavroula I.} and Alaa Abdul-Sada and Tizzard, {Graham J.} and Coles, {Simon J.} and Giulia Lorusso and Marco Evangelisti and Albert Escuer and Kostakis, {George E.}",
year = "2017",
month = sep,
day = "8",
doi = "10.1002/ejic.201700728",
language = "English",
volume = "2017",
pages = "3938--3945",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "33",

}

RIS

TY - JOUR

T1 - Heptanuclear Disk-Like MII 3LnIII 4 (M = Ni, Co) Coordination Clusters

T2 - Synthesis, Structures and Magnetic Properties

AU - Griffiths, Kieran

AU - Harding, Chris

AU - Dokorou, Vasiliki N.

AU - Loukopoulos, Edward

AU - Sampani, Stavroula I.

AU - Abdul-Sada, Alaa

AU - Tizzard, Graham J.

AU - Coles, Simon J.

AU - Lorusso, Giulia

AU - Evangelisti, Marco

AU - Escuer, Albert

AU - Kostakis, George E.

PY - 2017/9/8

Y1 - 2017/9/8

N2 - The synthesis, characterization, crystal structures and magnetic properties of isoskeletal heptanuclear disk-like MII 3LnIII 4 coordination clusters with the general formula [CoII 3LnIII 4(µ3-OH)6L6(CF3SO3)][(CF3SO3)5] where Ln = Gd (2), Y (3) and [NiII 3LnIII 4(µ3-OH)6L6(CF3SO3)][(CF3SO3)5] where Ln = Dy (4), Gd (5), Y (6) are presented. All the compounds are stable in solution as confirmed by ESI-MS. Magnetic studies were performed for compounds 2, 4, 5 and 6 and indicate ferromagnetic coupling while the magnetocaloric properties of 5 are characterized by ΔSm = –15.4 J kg–1 K–1 at T = 5.0 K and ΔTad = 5.9 K at T = 2.3 K, for µ0ΔH = 7 T.

AB - The synthesis, characterization, crystal structures and magnetic properties of isoskeletal heptanuclear disk-like MII 3LnIII 4 coordination clusters with the general formula [CoII 3LnIII 4(µ3-OH)6L6(CF3SO3)][(CF3SO3)5] where Ln = Gd (2), Y (3) and [NiII 3LnIII 4(µ3-OH)6L6(CF3SO3)][(CF3SO3)5] where Ln = Dy (4), Gd (5), Y (6) are presented. All the compounds are stable in solution as confirmed by ESI-MS. Magnetic studies were performed for compounds 2, 4, 5 and 6 and indicate ferromagnetic coupling while the magnetocaloric properties of 5 are characterized by ΔSm = –15.4 J kg–1 K–1 at T = 5.0 K and ΔTad = 5.9 K at T = 2.3 K, for µ0ΔH = 7 T.

KW - Cluster compounds

KW - Disk-like

KW - Magnetic properties

KW - Schiff bases

KW - Topology

U2 - 10.1002/ejic.201700728

DO - 10.1002/ejic.201700728

M3 - Journal article

AN - SCOPUS:85028968919

VL - 2017

SP - 3938

EP - 3945

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 33

ER -