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Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes

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Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes. / Kumar, Prashant; Lymperopoulou, Smaragda; Griffiths, Kieran et al.
In: Catalysts, Vol. 6, No. 9, 140, 12.09.2016.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Kumar P, Lymperopoulou S, Griffiths K, Sampani SI, Kostakis GE. Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes. Catalysts. 2016 Sept 12;6(9):140. doi: 10.3390/catal6090140

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@article{b26d30f5d68848328b591adb28160e86,
title = "Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes",
abstract = "We demonstrate for the first time the high efficacy of tetranuclear ZnII2LnIII2 coordination clusters (CCs) as catalysts for the Friedel-Crafts (FC) alkylation of indoles with a range of trans-β-nitrostyrenes. The reaction proceeds in good to excellent yields (76%-99%) at room temperature with catalyst loadings as low as 1.0 mol %.",
keywords = "Coordination clusters, Friedel-Crafts alkylation, Zn/4f",
author = "Prashant Kumar and Smaragda Lymperopoulou and Kieran Griffiths and Sampani, {Stavroula I.} and Kostakis, {George E.}",
year = "2016",
month = sep,
day = "12",
doi = "10.3390/catal6090140",
language = "English",
volume = "6",
journal = "Catalysts",
issn = "2073-4344",
publisher = "Multidisciplinary Digital Publishing Institute",
number = "9",

}

RIS

TY - JOUR

T1 - Highly efficient tetranuclear ZnII2LnIII2 catalysts for the friedel-crafts alkylation of indoles and nitrostyrenes

AU - Kumar, Prashant

AU - Lymperopoulou, Smaragda

AU - Griffiths, Kieran

AU - Sampani, Stavroula I.

AU - Kostakis, George E.

PY - 2016/9/12

Y1 - 2016/9/12

N2 - We demonstrate for the first time the high efficacy of tetranuclear ZnII2LnIII2 coordination clusters (CCs) as catalysts for the Friedel-Crafts (FC) alkylation of indoles with a range of trans-β-nitrostyrenes. The reaction proceeds in good to excellent yields (76%-99%) at room temperature with catalyst loadings as low as 1.0 mol %.

AB - We demonstrate for the first time the high efficacy of tetranuclear ZnII2LnIII2 coordination clusters (CCs) as catalysts for the Friedel-Crafts (FC) alkylation of indoles with a range of trans-β-nitrostyrenes. The reaction proceeds in good to excellent yields (76%-99%) at room temperature with catalyst loadings as low as 1.0 mol %.

KW - Coordination clusters

KW - Friedel-Crafts alkylation

KW - Zn/4f

U2 - 10.3390/catal6090140

DO - 10.3390/catal6090140

M3 - Journal article

AN - SCOPUS:84988354851

VL - 6

JO - Catalysts

JF - Catalysts

SN - 2073-4344

IS - 9

M1 - 140

ER -