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History effects in lithium-oxygen batteries: how initial seeding influences the discharge capacity

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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History effects in lithium-oxygen batteries: how initial seeding influences the discharge capacity. / Rinaldi, Ali; Wijaya, Olivia; Hoster, Harry E. et al.
In: ChemSusChem, Vol. 7, No. 5, 05.2014, p. 1283-1288.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Rinaldi, A, Wijaya, O, Hoster, HE & Yu, DYW 2014, 'History effects in lithium-oxygen batteries: how initial seeding influences the discharge capacity', ChemSusChem, vol. 7, no. 5, pp. 1283-1288. https://doi.org/10.1002/cssc.201300986

APA

Rinaldi, A., Wijaya, O., Hoster, H. E., & Yu, D. Y. W. (2014). History effects in lithium-oxygen batteries: how initial seeding influences the discharge capacity. ChemSusChem, 7(5), 1283-1288. https://doi.org/10.1002/cssc.201300986

Vancouver

Rinaldi A, Wijaya O, Hoster HE, Yu DYW. History effects in lithium-oxygen batteries: how initial seeding influences the discharge capacity. ChemSusChem. 2014 May;7(5):1283-1288. doi: 10.1002/cssc.201300986

Author

Rinaldi, Ali ; Wijaya, Olivia ; Hoster, Harry E. et al. / History effects in lithium-oxygen batteries : how initial seeding influences the discharge capacity. In: ChemSusChem. 2014 ; Vol. 7, No. 5. pp. 1283-1288.

Bibtex

@article{897d4df79fe84db79b16db2f0a930bcd,
title = "History effects in lithium-oxygen batteries: how initial seeding influences the discharge capacity",
abstract = "In laboratory experiments, Li-O-2 systems show sudden death at capacities far below the theoretical value. Identifying how discharge products limit the total capacity is crucial in Li-O-2 system. We investigated the effect of Li2O2 seed layer deposited on carbon cathode under potentiostatic conditions at increasing overpotentials to the subsequent slow discharge at galvanostatic condition. The discharge capacity attainable in the second step is found to vary by more than a factor of 3 depending on the history, i.e., the seed layer. These results provide evidence that the battery history is decisive for the total discharge capacities.",
keywords = "batteries, discharge overpotential, electrochemistry, lithium peroxide, seeding, RECHARGEABLE LI-O-2 BATTERIES, AIR BATTERIES, CARBON, ELECTROLYTES, ELECTROCHEMISTRY, PERFORMANCE, LIMITATIONS, ELECTRODES, TRANSPORT, SOLVENTS",
author = "Ali Rinaldi and Olivia Wijaya and Hoster, {Harry E.} and Yu, {Denis Y. W.}",
year = "2014",
month = may,
doi = "10.1002/cssc.201300986",
language = "English",
volume = "7",
pages = "1283--1288",
journal = "ChemSusChem",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "5",

}

RIS

TY - JOUR

T1 - History effects in lithium-oxygen batteries

T2 - how initial seeding influences the discharge capacity

AU - Rinaldi, Ali

AU - Wijaya, Olivia

AU - Hoster, Harry E.

AU - Yu, Denis Y. W.

PY - 2014/5

Y1 - 2014/5

N2 - In laboratory experiments, Li-O-2 systems show sudden death at capacities far below the theoretical value. Identifying how discharge products limit the total capacity is crucial in Li-O-2 system. We investigated the effect of Li2O2 seed layer deposited on carbon cathode under potentiostatic conditions at increasing overpotentials to the subsequent slow discharge at galvanostatic condition. The discharge capacity attainable in the second step is found to vary by more than a factor of 3 depending on the history, i.e., the seed layer. These results provide evidence that the battery history is decisive for the total discharge capacities.

AB - In laboratory experiments, Li-O-2 systems show sudden death at capacities far below the theoretical value. Identifying how discharge products limit the total capacity is crucial in Li-O-2 system. We investigated the effect of Li2O2 seed layer deposited on carbon cathode under potentiostatic conditions at increasing overpotentials to the subsequent slow discharge at galvanostatic condition. The discharge capacity attainable in the second step is found to vary by more than a factor of 3 depending on the history, i.e., the seed layer. These results provide evidence that the battery history is decisive for the total discharge capacities.

KW - batteries

KW - discharge overpotential

KW - electrochemistry

KW - lithium peroxide

KW - seeding

KW - RECHARGEABLE LI-O-2 BATTERIES

KW - AIR BATTERIES

KW - CARBON

KW - ELECTROLYTES

KW - ELECTROCHEMISTRY

KW - PERFORMANCE

KW - LIMITATIONS

KW - ELECTRODES

KW - TRANSPORT

KW - SOLVENTS

U2 - 10.1002/cssc.201300986

DO - 10.1002/cssc.201300986

M3 - Journal article

VL - 7

SP - 1283

EP - 1288

JO - ChemSusChem

JF - ChemSusChem

SN - 1864-5631

IS - 5

ER -