Home > Research > Publications & Outputs > Hydrogen production by glycerol steam reforming...

Research

Links

Text available via DOI:

View graph of relations

Hydrogen production by glycerol steam reforming with in situ hydrogen separation: A thermodynamic investigation

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Hydrogen production by glycerol steam reforming with in situ hydrogen separation: A thermodynamic investigation. / Wang, Xiaodong; Wang, N.; Li, M. et al.
In: International Journal of Hydrogen Energy, Vol. 35, No. 19, 2010, p. 10252-10256.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Wang, X, Wang, N, Li, M, Li, S, Wang, S & Ma, X 2010, 'Hydrogen production by glycerol steam reforming with in situ hydrogen separation: A thermodynamic investigation', International Journal of Hydrogen Energy, vol. 35, no. 19, pp. 10252-10256. https://doi.org/10.1016/j.ijhydene.2010.07.140

APA

Wang, X., Wang, N., Li, M., Li, S., Wang, S., & Ma, X. (2010). Hydrogen production by glycerol steam reforming with in situ hydrogen separation: A thermodynamic investigation. International Journal of Hydrogen Energy, 35(19), 10252-10256. https://doi.org/10.1016/j.ijhydene.2010.07.140

Vancouver

Wang X, Wang N, Li M, Li S, Wang S, Ma X. Hydrogen production by glycerol steam reforming with in situ hydrogen separation: A thermodynamic investigation. International Journal of Hydrogen Energy. 2010;35(19):10252-10256. doi: 10.1016/j.ijhydene.2010.07.140

Author

Wang, Xiaodong ; Wang, N. ; Li, M. et al. / Hydrogen production by glycerol steam reforming with in situ hydrogen separation : A thermodynamic investigation. In: International Journal of Hydrogen Energy. 2010 ; Vol. 35, No. 19. pp. 10252-10256.

Bibtex

@article{6d9fdc67429b4e5d8f253bc221b9a74a,
title = "Hydrogen production by glycerol steam reforming with in situ hydrogen separation: A thermodynamic investigation",
abstract = "Thermodynamic features of hydrogen production by glycerol steam reforming with in situ hydrogen extraction have been studied with the method of Gibbs free energy minimization. The effects of pressure (1–5 atm), temperature (600–1000 K), water to glycerol ratio (WGR, 3–12) and fraction of H2 removal (f, 0–1) on the reforming reactions and carbon formation were investigated. The results suggest separation of hydrogen in situ can substantially enhance hydrogen production from glycerol steam reforming, as 7 mol (stoichiometric value) of hydrogen can be obtained even at 600 K due to the hydrogen extraction. It is demonstrated that atmospheric pressure and a WGR of 9 are suitable for hydrogen production and the optimum temperature for glycerol steam reforming with in situ hydrogen removal is between 825 and 875 K, 100 K lower than that achieved typically without hydrogen separation. Furthermore, the detrimental influence of increasing pressure in terms of hydrogen production becomes marginal above 800 K with a high fraction of H2 removal (i.e., f = 0.99). High temperature and WGR are favorable to inhibit carbon production.",
author = "Xiaodong Wang and N. Wang and M. Li and S. Li and S. Wang and X. Ma",
year = "2010",
doi = "10.1016/j.ijhydene.2010.07.140",
language = "English",
volume = "35",
pages = "10252--10256",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Limited",
number = "19",

}

RIS

TY - JOUR

T1 - Hydrogen production by glycerol steam reforming with in situ hydrogen separation

T2 - A thermodynamic investigation

AU - Wang, Xiaodong

AU - Wang, N.

AU - Li, M.

AU - Li, S.

AU - Wang, S.

AU - Ma, X.

PY - 2010

Y1 - 2010

N2 - Thermodynamic features of hydrogen production by glycerol steam reforming with in situ hydrogen extraction have been studied with the method of Gibbs free energy minimization. The effects of pressure (1–5 atm), temperature (600–1000 K), water to glycerol ratio (WGR, 3–12) and fraction of H2 removal (f, 0–1) on the reforming reactions and carbon formation were investigated. The results suggest separation of hydrogen in situ can substantially enhance hydrogen production from glycerol steam reforming, as 7 mol (stoichiometric value) of hydrogen can be obtained even at 600 K due to the hydrogen extraction. It is demonstrated that atmospheric pressure and a WGR of 9 are suitable for hydrogen production and the optimum temperature for glycerol steam reforming with in situ hydrogen removal is between 825 and 875 K, 100 K lower than that achieved typically without hydrogen separation. Furthermore, the detrimental influence of increasing pressure in terms of hydrogen production becomes marginal above 800 K with a high fraction of H2 removal (i.e., f = 0.99). High temperature and WGR are favorable to inhibit carbon production.

AB - Thermodynamic features of hydrogen production by glycerol steam reforming with in situ hydrogen extraction have been studied with the method of Gibbs free energy minimization. The effects of pressure (1–5 atm), temperature (600–1000 K), water to glycerol ratio (WGR, 3–12) and fraction of H2 removal (f, 0–1) on the reforming reactions and carbon formation were investigated. The results suggest separation of hydrogen in situ can substantially enhance hydrogen production from glycerol steam reforming, as 7 mol (stoichiometric value) of hydrogen can be obtained even at 600 K due to the hydrogen extraction. It is demonstrated that atmospheric pressure and a WGR of 9 are suitable for hydrogen production and the optimum temperature for glycerol steam reforming with in situ hydrogen removal is between 825 and 875 K, 100 K lower than that achieved typically without hydrogen separation. Furthermore, the detrimental influence of increasing pressure in terms of hydrogen production becomes marginal above 800 K with a high fraction of H2 removal (i.e., f = 0.99). High temperature and WGR are favorable to inhibit carbon production.

U2 - 10.1016/j.ijhydene.2010.07.140

DO - 10.1016/j.ijhydene.2010.07.140

M3 - Journal article

VL - 35

SP - 10252

EP - 10256

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 19

ER -