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Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene

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Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene. / Li, Wei; Yang, Huaqin; Zhang, Jingjing et al.
In: Chemical Communications, Vol. 52, No. 74, 25.09.2016, p. 11092-11095.

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Li W, Yang H, Zhang J, Mu J, Gong D, Wang X. Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene. Chemical Communications. 2016 Sept 25;52(74):11092-11095. doi: 10.1039/C6CC04814E

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Li, Wei ; Yang, Huaqin ; Zhang, Jingjing et al. / Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene. In: Chemical Communications. 2016 ; Vol. 52, No. 74. pp. 11092-11095.

Bibtex

@article{a8fa467644c14a1ea0c0bbfdef50f776,
title = "Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene",
abstract = "Polyhedral oligomeric silsesquioxanes (POSSs) were adsorbed on methylaluminoxane-activated silica for the immobilization of fluorinated bis(phenoxyimine)Ti complexes (FI catalyst). These POSSs have been characterized as horizontal spacers isolating the active sites and hindering the chain overlap in polymerization. The heterogeneous catalyst exhibits considerable activity in the synthesis of weakly entangled polyethylene.",
author = "Wei Li and Huaqin Yang and Jingjing Zhang and Jingshan Mu and Dirong Gong and Xiaodong Wang",
year = "2016",
month = sep,
day = "25",
doi = "10.1039/C6CC04814E",
language = "English",
volume = "52",
pages = "11092--11095",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "74",

}

RIS

TY - JOUR

T1 - Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene

AU - Li, Wei

AU - Yang, Huaqin

AU - Zhang, Jingjing

AU - Mu, Jingshan

AU - Gong, Dirong

AU - Wang, Xiaodong

PY - 2016/9/25

Y1 - 2016/9/25

N2 - Polyhedral oligomeric silsesquioxanes (POSSs) were adsorbed on methylaluminoxane-activated silica for the immobilization of fluorinated bis(phenoxyimine)Ti complexes (FI catalyst). These POSSs have been characterized as horizontal spacers isolating the active sites and hindering the chain overlap in polymerization. The heterogeneous catalyst exhibits considerable activity in the synthesis of weakly entangled polyethylene.

AB - Polyhedral oligomeric silsesquioxanes (POSSs) were adsorbed on methylaluminoxane-activated silica for the immobilization of fluorinated bis(phenoxyimine)Ti complexes (FI catalyst). These POSSs have been characterized as horizontal spacers isolating the active sites and hindering the chain overlap in polymerization. The heterogeneous catalyst exhibits considerable activity in the synthesis of weakly entangled polyethylene.

U2 - 10.1039/C6CC04814E

DO - 10.1039/C6CC04814E

M3 - Journal article

VL - 52

SP - 11092

EP - 11095

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 74

ER -