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Inorganic arsenic and selenium determination using miniaturised isotachophoresis

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Inorganic arsenic and selenium determination using miniaturised isotachophoresis. / Prest, J. E.; Baldock, S. J.; Fielden, P. R. et al.
In: Microchimica Acta, Vol. 151, No. 3-4, 11.2005, p. 223-230.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Prest, JE, Baldock, SJ, Fielden, PR, Goddard, NJ & Brown, BJT 2005, 'Inorganic arsenic and selenium determination using miniaturised isotachophoresis', Microchimica Acta, vol. 151, no. 3-4, pp. 223-230. https://doi.org/10.1007/s00604-005-0403-y

APA

Prest, J. E., Baldock, S. J., Fielden, P. R., Goddard, N. J., & Brown, B. J. T. (2005). Inorganic arsenic and selenium determination using miniaturised isotachophoresis. Microchimica Acta, 151(3-4), 223-230. https://doi.org/10.1007/s00604-005-0403-y

Vancouver

Prest JE, Baldock SJ, Fielden PR, Goddard NJ, Brown BJT. Inorganic arsenic and selenium determination using miniaturised isotachophoresis. Microchimica Acta. 2005 Nov;151(3-4):223-230. Epub 2005 Oct 14. doi: 10.1007/s00604-005-0403-y

Author

Prest, J. E. ; Baldock, S. J. ; Fielden, P. R. et al. / Inorganic arsenic and selenium determination using miniaturised isotachophoresis. In: Microchimica Acta. 2005 ; Vol. 151, No. 3-4. pp. 223-230.

Bibtex

@article{4f5bd74cb7b34e118cf91f6eb4f144b5,
title = "Inorganic arsenic and selenium determination using miniaturised isotachophoresis",
abstract = "A new method allowing the simultaneous determination of arsenic(V), selenium(IV) and selenium(VI) using miniaturised isotachophoresis has been developed. The method uses 0.02 M nitric acid buffered to pH 5.5 with histidine as the leading electrolyte. Using a miniaturised poly(methyl methacrylate) chip device with an integrated conductivity detector, separations of model samples and an industrial process stream sample were achieved. Limits of detection were calculated to be 0.85 mg L−1 for arsenic(V), 0.95 mg L−1 for selenium(IV) and 1.0 mg L−1 for selenium(VI). A method for the analysis of arsenic(III), using a glycolic acid based leading electrolyte to eliminate carbonate interference is also presented.",
keywords = "Isotachophoresis, Miniaturisation, chip, Arsenic, Selenium",
author = "Prest, {J. E.} and Baldock, {S. J.} and Fielden, {P. R.} and Goddard, {N. J.} and Brown, {B. J. T.}",
year = "2005",
month = nov,
doi = "10.1007/s00604-005-0403-y",
language = "English",
volume = "151",
pages = "223--230",
journal = "Microchimica Acta",
issn = "0026-3672",
publisher = "Springer Wien",
number = "3-4",

}

RIS

TY - JOUR

T1 - Inorganic arsenic and selenium determination using miniaturised isotachophoresis

AU - Prest, J. E.

AU - Baldock, S. J.

AU - Fielden, P. R.

AU - Goddard, N. J.

AU - Brown, B. J. T.

PY - 2005/11

Y1 - 2005/11

N2 - A new method allowing the simultaneous determination of arsenic(V), selenium(IV) and selenium(VI) using miniaturised isotachophoresis has been developed. The method uses 0.02 M nitric acid buffered to pH 5.5 with histidine as the leading electrolyte. Using a miniaturised poly(methyl methacrylate) chip device with an integrated conductivity detector, separations of model samples and an industrial process stream sample were achieved. Limits of detection were calculated to be 0.85 mg L−1 for arsenic(V), 0.95 mg L−1 for selenium(IV) and 1.0 mg L−1 for selenium(VI). A method for the analysis of arsenic(III), using a glycolic acid based leading electrolyte to eliminate carbonate interference is also presented.

AB - A new method allowing the simultaneous determination of arsenic(V), selenium(IV) and selenium(VI) using miniaturised isotachophoresis has been developed. The method uses 0.02 M nitric acid buffered to pH 5.5 with histidine as the leading electrolyte. Using a miniaturised poly(methyl methacrylate) chip device with an integrated conductivity detector, separations of model samples and an industrial process stream sample were achieved. Limits of detection were calculated to be 0.85 mg L−1 for arsenic(V), 0.95 mg L−1 for selenium(IV) and 1.0 mg L−1 for selenium(VI). A method for the analysis of arsenic(III), using a glycolic acid based leading electrolyte to eliminate carbonate interference is also presented.

KW - Isotachophoresis

KW - Miniaturisation

KW - chip

KW - Arsenic

KW - Selenium

U2 - 10.1007/s00604-005-0403-y

DO - 10.1007/s00604-005-0403-y

M3 - Journal article

VL - 151

SP - 223

EP - 230

JO - Microchimica Acta

JF - Microchimica Acta

SN - 0026-3672

IS - 3-4

ER -