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Isotopic labelling in the study of organic and organometallic mechanism and structure: an account

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Isotopic labelling in the study of organic and organometallic mechanism and structure: an account. / Lloyd-Jones, Guy C.; Munoz-Herranz, Maria.
In: Journal of Labelled Compounds and Radiopharmaceuticals, Vol. 50, No. 11-12, 01.10.2007, p. 1072-1087.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Lloyd-Jones, GC & Munoz-Herranz, M 2007, 'Isotopic labelling in the study of organic and organometallic mechanism and structure: an account', Journal of Labelled Compounds and Radiopharmaceuticals, vol. 50, no. 11-12, pp. 1072-1087. https://doi.org/10.1002/jlcr.1382

APA

Lloyd-Jones, G. C., & Munoz-Herranz, M. (2007). Isotopic labelling in the study of organic and organometallic mechanism and structure: an account. Journal of Labelled Compounds and Radiopharmaceuticals, 50(11-12), 1072-1087. https://doi.org/10.1002/jlcr.1382

Vancouver

Lloyd-Jones GC, Munoz-Herranz M. Isotopic labelling in the study of organic and organometallic mechanism and structure: an account. Journal of Labelled Compounds and Radiopharmaceuticals. 2007 Oct 1;50(11-12):1072-1087. doi: 10.1002/jlcr.1382

Author

Lloyd-Jones, Guy C. ; Munoz-Herranz, Maria. / Isotopic labelling in the study of organic and organometallic mechanism and structure: an account. In: Journal of Labelled Compounds and Radiopharmaceuticals. 2007 ; Vol. 50, No. 11-12. pp. 1072-1087.

Bibtex

@article{67b5dfbc829a4d369d296839e0b1de4f,
title = "Isotopic labelling in the study of organic and organometallic mechanism and structure: an account",
abstract = "An account of the use of stable isotopes (2H, 13C, 15N, 18O, 34S) for the study of organic and organometallic reaction mechanism and structure, by way of kinetic determinations and modelling, NMR spectroscopy and mass spectrometry is presented. The techniques discussed include use of kinetic isotope effects, label-facilitated nOe experiments, cross-over experiments, stereoisotopochemical analysis, label-facilitated NMR analysis of enantiomers using chiral-shift reagents and NMR in chiral liquid crystal matrices. The reactions in which these tools have been applied are {\ss}-H elimination in Pd-s-alkyl complexes, the Bayliss–Hilman reaction, C–H insertion of stable carbenes, ring-closing metathesis reactions, palladium-catalysed hydrosilyation, palladium-catalysed cycloisomerization, anionic thia-Fries rearrangements, synthesis of proton sponges and their nitrogen stereodynamics, and transition metal (Pd, Mo) catalysed allylic alkylation",
author = "Lloyd-Jones, {Guy C.} and Maria Munoz-Herranz",
year = "2007",
month = oct,
day = "1",
doi = "10.1002/jlcr.1382",
language = "English",
volume = "50",
pages = "1072--1087",
journal = "Journal of Labelled Compounds and Radiopharmaceuticals",
issn = "0362-4803",
publisher = "John Wiley and Sons Ltd",
number = "11-12",

}

RIS

TY - JOUR

T1 - Isotopic labelling in the study of organic and organometallic mechanism and structure: an account

AU - Lloyd-Jones, Guy C.

AU - Munoz-Herranz, Maria

PY - 2007/10/1

Y1 - 2007/10/1

N2 - An account of the use of stable isotopes (2H, 13C, 15N, 18O, 34S) for the study of organic and organometallic reaction mechanism and structure, by way of kinetic determinations and modelling, NMR spectroscopy and mass spectrometry is presented. The techniques discussed include use of kinetic isotope effects, label-facilitated nOe experiments, cross-over experiments, stereoisotopochemical analysis, label-facilitated NMR analysis of enantiomers using chiral-shift reagents and NMR in chiral liquid crystal matrices. The reactions in which these tools have been applied are ß-H elimination in Pd-s-alkyl complexes, the Bayliss–Hilman reaction, C–H insertion of stable carbenes, ring-closing metathesis reactions, palladium-catalysed hydrosilyation, palladium-catalysed cycloisomerization, anionic thia-Fries rearrangements, synthesis of proton sponges and their nitrogen stereodynamics, and transition metal (Pd, Mo) catalysed allylic alkylation

AB - An account of the use of stable isotopes (2H, 13C, 15N, 18O, 34S) for the study of organic and organometallic reaction mechanism and structure, by way of kinetic determinations and modelling, NMR spectroscopy and mass spectrometry is presented. The techniques discussed include use of kinetic isotope effects, label-facilitated nOe experiments, cross-over experiments, stereoisotopochemical analysis, label-facilitated NMR analysis of enantiomers using chiral-shift reagents and NMR in chiral liquid crystal matrices. The reactions in which these tools have been applied are ß-H elimination in Pd-s-alkyl complexes, the Bayliss–Hilman reaction, C–H insertion of stable carbenes, ring-closing metathesis reactions, palladium-catalysed hydrosilyation, palladium-catalysed cycloisomerization, anionic thia-Fries rearrangements, synthesis of proton sponges and their nitrogen stereodynamics, and transition metal (Pd, Mo) catalysed allylic alkylation

U2 - 10.1002/jlcr.1382

DO - 10.1002/jlcr.1382

M3 - Journal article

VL - 50

SP - 1072

EP - 1087

JO - Journal of Labelled Compounds and Radiopharmaceuticals

JF - Journal of Labelled Compounds and Radiopharmaceuticals

SN - 0362-4803

IS - 11-12

ER -