Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Kinetic study on 2-methyl-1-butanol dehydration catalysed by ion exchange resin
AU - Aiouache, Farid
AU - Goto, Shigeo
PY - 2002/5
Y1 - 2002/5
N2 - The dehydration of 2-methyl 1-butanol (2M1BOH) in the liquid phase was studied by using an ion-exchange resin, Amberlyst 15 in the H+ form. Experiments were carried out in a batch reactor with the dry resin as a catalyst. Considering the inhibition effect of water, the rate expressions based on the Langmuir-Hinshelwood model were formulated. The sorption equilibrium model between liquid and resin phases during resin swelling was included in kinetic modelling. The cross-linked ion-exchange resin was highly selective to water at the beginning of the reaction. The experimental results agreed well with the calculated ones.
AB - The dehydration of 2-methyl 1-butanol (2M1BOH) in the liquid phase was studied by using an ion-exchange resin, Amberlyst 15 in the H+ form. Experiments were carried out in a batch reactor with the dry resin as a catalyst. Considering the inhibition effect of water, the rate expressions based on the Langmuir-Hinshelwood model were formulated. The sorption equilibrium model between liquid and resin phases during resin swelling was included in kinetic modelling. The cross-linked ion-exchange resin was highly selective to water at the beginning of the reaction. The experimental results agreed well with the calculated ones.
M3 - Journal article
VL - 35
SP - 436
EP - 442
JO - Journal of Chemical Engineering of Japan
JF - Journal of Chemical Engineering of Japan
SN - 0021-9592
IS - 5
ER -