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Lanthanide complexes as chiral probes exploiting circularly polarized luminescence

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Lanthanide complexes as chiral probes exploiting circularly polarized luminescence. / Carr, Rachel; Evans, Nicholas H.; Parker, David.
In: Chemical Society Reviews, Vol. 41, No. 23, 07.12.2012, p. 7673-7686.

Research output: Contribution to Journal/Magazine › Literature review › peer-review

Harvard

Carr, R, Evans, NH & Parker, D 2012, 'Lanthanide complexes as chiral probes exploiting circularly polarized luminescence', Chemical Society Reviews, vol. 41, no. 23, pp. 7673-7686. https://doi.org/10.1039/c2cs35242g

APA

Carr, R., Evans, N. H., & Parker, D. (2012). Lanthanide complexes as chiral probes exploiting circularly polarized luminescence. Chemical Society Reviews, 41(23), 7673-7686. https://doi.org/10.1039/c2cs35242g

Vancouver

Carr R, Evans NH, Parker D. Lanthanide complexes as chiral probes exploiting circularly polarized luminescence. Chemical Society Reviews. 2012 Dec 7;41(23):7673-7686. doi: 10.1039/c2cs35242g

Author

Carr, Rachel ; Evans, Nicholas H. ; Parker, David. / Lanthanide complexes as chiral probes exploiting circularly polarized luminescence. In: Chemical Society Reviews. 2012 ; Vol. 41, No. 23. pp. 7673-7686.

Bibtex

@article{9dd1e61569604600aba54ffef3f95fa9,
title = "Lanthanide complexes as chiral probes exploiting circularly polarized luminescence",
abstract = "Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide ions are ideally suited for CPL spectroscopy and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis. The perturbation of a dynamically racemic complex may occur either by a change in complex constitution or by non-covalent association. With complexes of enantiopure ligands, perturbation may involve either dynamic helicity inversion or a reversible change in the lanthanide coordination environment.",
keywords = "POLYMETHYLATED DOTA LIGANDS, ENERGY-TRANSFER PROCESSES, AQUEOUS-SOLUTION, OPTICAL-ACTIVITY, AMINO-ACIDS, CHIROPTICAL LUMINESCENCE, TB(2,6-PYRIDINEDICARBOXYLATE)3(3-) LUMINESCENCE, RESOLVED RU(1,10-PHENANTHROLINE)3(2+), TRIS PYRIDINE-2,6-DICARBOXYLATE, VITAMIN-B-12 DERIVATIVES",
author = "Rachel Carr and Evans, {Nicholas H.} and David Parker",
year = "2012",
month = dec,
day = "7",
doi = "10.1039/c2cs35242g",
language = "English",
volume = "41",
pages = "7673--7686",
journal = "Chemical Society Reviews",
issn = "0306-0012",
publisher = "American Chemical Society",
number = "23",

}

RIS

TY - JOUR

T1 - Lanthanide complexes as chiral probes exploiting circularly polarized luminescence

AU - Carr, Rachel

AU - Evans, Nicholas H.

AU - Parker, David

PY - 2012/12/7

Y1 - 2012/12/7

N2 - Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide ions are ideally suited for CPL spectroscopy and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis. The perturbation of a dynamically racemic complex may occur either by a change in complex constitution or by non-covalent association. With complexes of enantiopure ligands, perturbation may involve either dynamic helicity inversion or a reversible change in the lanthanide coordination environment.

AB - Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide ions are ideally suited for CPL spectroscopy and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis. The perturbation of a dynamically racemic complex may occur either by a change in complex constitution or by non-covalent association. With complexes of enantiopure ligands, perturbation may involve either dynamic helicity inversion or a reversible change in the lanthanide coordination environment.

KW - POLYMETHYLATED DOTA LIGANDS

KW - ENERGY-TRANSFER PROCESSES

KW - AQUEOUS-SOLUTION

KW - OPTICAL-ACTIVITY

KW - AMINO-ACIDS

KW - CHIROPTICAL LUMINESCENCE

KW - TB(2,6-PYRIDINEDICARBOXYLATE)3(3-) LUMINESCENCE

KW - RESOLVED RU(1,10-PHENANTHROLINE)3(2+)

KW - TRIS PYRIDINE-2,6-DICARBOXYLATE

KW - VITAMIN-B-12 DERIVATIVES

U2 - 10.1039/c2cs35242g

DO - 10.1039/c2cs35242g

M3 - Literature review

VL - 41

SP - 7673

EP - 7686

JO - Chemical Society Reviews

JF - Chemical Society Reviews

SN - 0306-0012

IS - 23

ER -