Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
"Ligand-free" cluster quantized charging in an ionic liquid. / Mertens, S.F.L.; Vollmer, C.; Held, A. et al.
In: Angewandte Chemie International Edition, Vol. 50, No. 41, 2011, p. 9735-9738.Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - "Ligand-free" cluster quantized charging in an ionic liquid
AU - Mertens, S.F.L.
AU - Vollmer, C.
AU - Held, A.
AU - Aguirre, M.H.
AU - Walter, M.
AU - Janiak, C.
AU - Wandlowski, T.
PY - 2011
Y1 - 2011
N2 - On a charge: The experimental capacitance per cluster (C) as a function of charge state (z, see picture) confirms the quantized charging of "ligand-free" metal clusters in an ionic liquid. DFT calculations indicate a switch in orientation of the ionic shell around the clusters when the sign of the charge changes, and explain the maximum capacitance at zero charge. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
AB - On a charge: The experimental capacitance per cluster (C) as a function of charge state (z, see picture) confirms the quantized charging of "ligand-free" metal clusters in an ionic liquid. DFT calculations indicate a switch in orientation of the ionic shell around the clusters when the sign of the charge changes, and explain the maximum capacitance at zero charge. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KW - clusters
KW - density functional calculations
KW - gold
KW - ionic liquids
KW - quantized charging
KW - Charge state
KW - Density-functional calculations
KW - DFT calculation
KW - Ligand-free
KW - Metal cluster
KW - Quantized charging
KW - Zero charge
KW - Capacitance
KW - Gold
KW - Ligands
KW - Ionic liquids
U2 - 10.1002/anie.201104381
DO - 10.1002/anie.201104381
M3 - Journal article
VL - 50
SP - 9735
EP - 9738
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 41
ER -