Home > Research > Publications & Outputs > Lone-pair effects and structural trends in xSNO...

Research

Links

Text available via DOI:

Keywords

View graph of relations

Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance. / Holland, D.; Howes, A.P.; Smith, M.E. et al.
In: Journal of Physics: Condensed Matter, Vol. 14, No. 49, 2002, p. 13609-13621.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Holland, D, Howes, AP, Smith, ME & Hannon, AC 2002, 'Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance', Journal of Physics: Condensed Matter, vol. 14, no. 49, pp. 13609-13621. https://doi.org/10.1088/0953-8984/14/49/315

APA

Holland, D., Howes, A. P., Smith, M. E., & Hannon, A. C. (2002). Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance. Journal of Physics: Condensed Matter, 14(49), 13609-13621. https://doi.org/10.1088/0953-8984/14/49/315

Vancouver

Holland D, Howes AP, Smith ME, Hannon AC. Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance. Journal of Physics: Condensed Matter. 2002;14(49):13609-13621. doi: 10.1088/0953-8984/14/49/315

Author

Holland, D. ; Howes, A.P. ; Smith, M.E. et al. / Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance. In: Journal of Physics: Condensed Matter. 2002 ; Vol. 14, No. 49. pp. 13609-13621.

Bibtex

@article{e8b06199ba394c9396305a5f57917c13,
title = "Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance",
abstract = "Tin phosphate glasses, of general formula xSnO·(1 - x)P2O5(0.3 < x < 0.8), have been prepared by conventional melt-quench techniques and their structures studied using 31P and 119Sn nuclear magnetic resonance. The distribution of [PO4] Qn species changes with composition in accordance with the simple binary model, and the changes in chemical shift can be explained by the redistribution of electron charge from the P=O double bond. Sn(II) is found to occupy a highly asymmetric site, typical of a sterically active lone pair of electrons. The 119Sn parameters of the chemical shift tensor change systematically with x, reflecting the change in local environment from one where the next nearest neighbours are predominantly Q2 phosphorus to one where they are predominantly Q0 phosphorus.",
keywords = "Chemical bonds, Composition, Electrons, Nuclear magnetic resonance spectroscopy, Phosphorus, Tin compounds, Chemical shift tensor, Conventional melt-quench techniques, Electron charge, Lone-pair effects, Tin phosphate glasses, Glass",
author = "D. Holland and A.P. Howes and M.E. Smith and A.C. Hannon",
year = "2002",
doi = "10.1088/0953-8984/14/49/315",
language = "English",
volume = "14",
pages = "13609--13621",
journal = "Journal of Physics: Condensed Matter",
issn = "0953-8984",
publisher = "IOP Publishing Ltd",
number = "49",

}

RIS

TY - JOUR

T1 - Lone-pair effects and structural trends in xSNO·(1-x)P2O5 glasses deduced from 31P and 119Sn nuclear magnetic resonance

AU - Holland, D.

AU - Howes, A.P.

AU - Smith, M.E.

AU - Hannon, A.C.

PY - 2002

Y1 - 2002

N2 - Tin phosphate glasses, of general formula xSnO·(1 - x)P2O5(0.3 < x < 0.8), have been prepared by conventional melt-quench techniques and their structures studied using 31P and 119Sn nuclear magnetic resonance. The distribution of [PO4] Qn species changes with composition in accordance with the simple binary model, and the changes in chemical shift can be explained by the redistribution of electron charge from the P=O double bond. Sn(II) is found to occupy a highly asymmetric site, typical of a sterically active lone pair of electrons. The 119Sn parameters of the chemical shift tensor change systematically with x, reflecting the change in local environment from one where the next nearest neighbours are predominantly Q2 phosphorus to one where they are predominantly Q0 phosphorus.

AB - Tin phosphate glasses, of general formula xSnO·(1 - x)P2O5(0.3 < x < 0.8), have been prepared by conventional melt-quench techniques and their structures studied using 31P and 119Sn nuclear magnetic resonance. The distribution of [PO4] Qn species changes with composition in accordance with the simple binary model, and the changes in chemical shift can be explained by the redistribution of electron charge from the P=O double bond. Sn(II) is found to occupy a highly asymmetric site, typical of a sterically active lone pair of electrons. The 119Sn parameters of the chemical shift tensor change systematically with x, reflecting the change in local environment from one where the next nearest neighbours are predominantly Q2 phosphorus to one where they are predominantly Q0 phosphorus.

KW - Chemical bonds

KW - Composition

KW - Electrons

KW - Nuclear magnetic resonance spectroscopy

KW - Phosphorus

KW - Tin compounds

KW - Chemical shift tensor

KW - Conventional melt-quench techniques

KW - Electron charge

KW - Lone-pair effects

KW - Tin phosphate glasses

KW - Glass

U2 - 10.1088/0953-8984/14/49/315

DO - 10.1088/0953-8984/14/49/315

M3 - Journal article

VL - 14

SP - 13609

EP - 13621

JO - Journal of Physics: Condensed Matter

JF - Journal of Physics: Condensed Matter

SN - 0953-8984

IS - 49

ER -