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Macrocycles, Catenanes and Rotaxanes

Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSNChapter (peer-reviewed)peer-review

Publication date25/08/2021
Host publicationReactivity in Confined Spaces
EditorsRoss S. Forgan, Gareth O. Lloyd
Place of PublicationLondon
PublisherRoyal Society of Chemistry
Number of pages28
<mark>Original language</mark>English


Inspired by the myriad enzymes found in living organisms, supramolecular chemists have investigated the cavities of both macrocycles and the related interlocked molecules catenanes and rotaxanes as catalytic and non-catalytic sites of chemical reactions. While macrocycles are typically easier to access synthetically, the interlocked structures of catenanes and rotaxanes offer exciting opportunities, including their innate three-dimensionality, large-amplitude motion of their interlocked components and chirality arising from the mechanical bond.