Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Mechanistic insights of 2,4-D sorption onto biochar
T2 - Influence of feedstock materials and biochar properties
AU - Mandal, S
AU - Sarkar, B
AU - Igalavithana, AD
AU - Ok, YS
AU - Yang, X
AU - Lombi, E
AU - Bolan, N
PY - 2017/7/16
Y1 - 2017/7/16
N2 - Objective of this study was to investigate the mechanisms of 2,4-Dichlorophynoxy acetic acid (2,4-D) sorption on biochar in aqueous solutions. Sorption isotherm, kinetics, and desorption experiments were performed to identify the role of biochars’ feedstock and production conditions on 2,4-D sorption. Biochars were prepared from various green wastes (tea, burcucumber, and hardwood) at two pyrolytic temperatures (400 and 700 °C). The tea waste biochar produced at 700 °C was further activated with steam under a controlled flow. The sorption of 2,4-D was strongly dependent on the biochar properties such as specific surface area, surface functional groups, and microporosity. The steam activated biochar produced from tea waste showed the highest (58.8 mg g−1) 2,4-D sorption capacity, which was attributed to the high specific surface area (576 m2 g−1). The mechanism of 2,4-D removal from aqueous solution by biochar is mainly attributed to the formation of heterogeneous sorption sites due to the steam activation.
AB - Objective of this study was to investigate the mechanisms of 2,4-Dichlorophynoxy acetic acid (2,4-D) sorption on biochar in aqueous solutions. Sorption isotherm, kinetics, and desorption experiments were performed to identify the role of biochars’ feedstock and production conditions on 2,4-D sorption. Biochars were prepared from various green wastes (tea, burcucumber, and hardwood) at two pyrolytic temperatures (400 and 700 °C). The tea waste biochar produced at 700 °C was further activated with steam under a controlled flow. The sorption of 2,4-D was strongly dependent on the biochar properties such as specific surface area, surface functional groups, and microporosity. The steam activated biochar produced from tea waste showed the highest (58.8 mg g−1) 2,4-D sorption capacity, which was attributed to the high specific surface area (576 m2 g−1). The mechanism of 2,4-D removal from aqueous solution by biochar is mainly attributed to the formation of heterogeneous sorption sites due to the steam activation.
U2 - 10.1016/j.biortech.2017.07.073
DO - 10.1016/j.biortech.2017.07.073
M3 - Journal article
C2 - 28756126
VL - 246
SP - 160
EP - 167
JO - Bioresource Technology
JF - Bioresource Technology
SN - 0960-8524
ER -