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    Rights statement: This is the author’s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, 46, 45, 2021 DOI: 10.1016/j.ijhydene.2020.12.181

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Metal organic frameworks for hydrogen purification

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Metal organic frameworks for hydrogen purification. / Mao, D.; Griffin, J.M.; Dawson, R. et al.
In: International Journal of Hydrogen Energy, Vol. 46, No. 45, 31.07.2021, p. 23380-23405.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Mao, D, Griffin, JM, Dawson, R, Fairhurst, A & Bimbo, N 2021, 'Metal organic frameworks for hydrogen purification', International Journal of Hydrogen Energy, vol. 46, no. 45, pp. 23380-23405. https://doi.org/10.1016/j.ijhydene.2020.12.181

APA

Vancouver

Mao D, Griffin JM, Dawson R, Fairhurst A, Bimbo N. Metal organic frameworks for hydrogen purification. International Journal of Hydrogen Energy. 2021 Jul 31;46(45):23380-23405. Epub 2021 Jan 28. doi: 10.1016/j.ijhydene.2020.12.181

Author

Mao, D. ; Griffin, J.M. ; Dawson, R. et al. / Metal organic frameworks for hydrogen purification. In: International Journal of Hydrogen Energy. 2021 ; Vol. 46, No. 45. pp. 23380-23405.

Bibtex

@article{526f9af53a644f2eb5d57f57f6f58b08,
title = "Metal organic frameworks for hydrogen purification",
abstract = "High purity hydrogen is one of the key factors in determining the lifetime of proton exchange membrane (PEM) fuel cells. However, the current industrial processes for producing high purity hydrogen are not only expensive, but also come with low energy efficiencies and productivity. Finding more cost-effective methods of purifying hydrogen is essential for ensuring wider scale deployment of PEM fuel cells. Among various hydrogen purification methods, adsorption in porous materials and membrane technologies are seen as two of the most promising candidates for the current industrial hydrogen purification methods, with metal organic frameworks (MOF) being particularly popular in research over the last decade. Despite many available reviews on MOFs, most focus on synthesis and production, with few reports focused on performance for hydrogen purification. This review describes the working principle and performance parameters of adsorptive separations and membrane materials and identifies MOFs that have been reported for hydrogen purification. The MOFs are summarised and their performance in separating hydrogen from common impurities (CO2, N2, CH4, CO) is compared systematically. The challenges of commercial application of MOFs for hydrogen purification are discussed. {\textcopyright} 2020 Hydrogen Energy Publications LLC",
keywords = "Hydrogen purification, Metal organic frameworks, MOFs, Zeolitic imidazolate frameworks, Cost effectiveness, Industrial research, Membrane technology, Metal-Organic Frameworks, Organometallics, Porous materials, Purification, Adsorptive separation, Commercial applications, Cost-effective methods, Industrial processs, Membrane material, PEM fuel cell, Performance parameters, Proton exchange membrane fuel cells (PEMFC)",
author = "D. Mao and J.M. Griffin and R. Dawson and A. Fairhurst and N. Bimbo",
note = "This is the author{\textquoteright}s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, 46, 45, 2021 DOI: 10.1016/j.ijhydene.2020.12.181",
year = "2021",
month = jul,
day = "31",
doi = "10.1016/j.ijhydene.2020.12.181",
language = "English",
volume = "46",
pages = "23380--23405",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Limited",
number = "45",

}

RIS

TY - JOUR

T1 - Metal organic frameworks for hydrogen purification

AU - Mao, D.

AU - Griffin, J.M.

AU - Dawson, R.

AU - Fairhurst, A.

AU - Bimbo, N.

N1 - This is the author’s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, 46, 45, 2021 DOI: 10.1016/j.ijhydene.2020.12.181

PY - 2021/7/31

Y1 - 2021/7/31

N2 - High purity hydrogen is one of the key factors in determining the lifetime of proton exchange membrane (PEM) fuel cells. However, the current industrial processes for producing high purity hydrogen are not only expensive, but also come with low energy efficiencies and productivity. Finding more cost-effective methods of purifying hydrogen is essential for ensuring wider scale deployment of PEM fuel cells. Among various hydrogen purification methods, adsorption in porous materials and membrane technologies are seen as two of the most promising candidates for the current industrial hydrogen purification methods, with metal organic frameworks (MOF) being particularly popular in research over the last decade. Despite many available reviews on MOFs, most focus on synthesis and production, with few reports focused on performance for hydrogen purification. This review describes the working principle and performance parameters of adsorptive separations and membrane materials and identifies MOFs that have been reported for hydrogen purification. The MOFs are summarised and their performance in separating hydrogen from common impurities (CO2, N2, CH4, CO) is compared systematically. The challenges of commercial application of MOFs for hydrogen purification are discussed. © 2020 Hydrogen Energy Publications LLC

AB - High purity hydrogen is one of the key factors in determining the lifetime of proton exchange membrane (PEM) fuel cells. However, the current industrial processes for producing high purity hydrogen are not only expensive, but also come with low energy efficiencies and productivity. Finding more cost-effective methods of purifying hydrogen is essential for ensuring wider scale deployment of PEM fuel cells. Among various hydrogen purification methods, adsorption in porous materials and membrane technologies are seen as two of the most promising candidates for the current industrial hydrogen purification methods, with metal organic frameworks (MOF) being particularly popular in research over the last decade. Despite many available reviews on MOFs, most focus on synthesis and production, with few reports focused on performance for hydrogen purification. This review describes the working principle and performance parameters of adsorptive separations and membrane materials and identifies MOFs that have been reported for hydrogen purification. The MOFs are summarised and their performance in separating hydrogen from common impurities (CO2, N2, CH4, CO) is compared systematically. The challenges of commercial application of MOFs for hydrogen purification are discussed. © 2020 Hydrogen Energy Publications LLC

KW - Hydrogen purification

KW - Metal organic frameworks

KW - MOFs

KW - Zeolitic imidazolate frameworks

KW - Cost effectiveness

KW - Industrial research

KW - Membrane technology

KW - Metal-Organic Frameworks

KW - Organometallics

KW - Porous materials

KW - Purification

KW - Adsorptive separation

KW - Commercial applications

KW - Cost-effective methods

KW - Industrial processs

KW - Membrane material

KW - PEM fuel cell

KW - Performance parameters

KW - Proton exchange membrane fuel cells (PEMFC)

U2 - 10.1016/j.ijhydene.2020.12.181

DO - 10.1016/j.ijhydene.2020.12.181

M3 - Journal article

VL - 46

SP - 23380

EP - 23405

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 45

ER -