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Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium

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Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium. / Garcia, Maria P.; Green, Michael; Stone, F. Gordon A. et al.
In: Dalton Transactions, Vol. 1985, No. 11, 1985, p. 2343-2348.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Garcia, MP, Green, M, Stone, FGA, Somerville, RG, Welch, AJ, Briant, CE, Cox, D & Mingos, DMP 1985, 'Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium', Dalton Transactions, vol. 1985, no. 11, pp. 2343-2348. https://doi.org/10.1039/dt9850002343

APA

Garcia, M. P., Green, M., Stone, F. G. A., Somerville, R. G., Welch, A. J., Briant, C. E., Cox, D., & Mingos, D. M. P. (1985). Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium. Dalton Transactions, 1985(11), 2343-2348. https://doi.org/10.1039/dt9850002343

Vancouver

Garcia MP, Green M, Stone FGA, Somerville RG, Welch AJ, Briant CE et al. Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium. Dalton Transactions. 1985;1985(11):2343-2348. doi: 10.1039/dt9850002343

Author

Garcia, Maria P. ; Green, Michael ; Stone, F. Gordon A. et al. / Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium. In: Dalton Transactions. 1985 ; Vol. 1985, No. 11. pp. 2343-2348.

Bibtex

@article{0fce41c2654045f8958094fb1f882728,
title = "Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium",
abstract = "Icosahedral 2,4-dicarba-1-ferraboranes with η6-bonded benzene, toluene, o-xylene, or naphthalene ligands have been synthesised in moderate yields by reaction of [Fe(cod)(η5-C5H5)](cod = cyclo-octa-1,5-diene) with 2,3-Me2-2,3-C2B9H9 in the presence of the appropriate arene. In addition, the toluene derivative, closo-[1-(η6-C6H5Me)-2,4-Me2-1,2,4-FeC2B9H9](2), has also been obtained by treatment of the carbaborane with [Fe2(µ-η-C6Me6)(η5-C5H5)2] in toluene. Reaction of [RuCl2(η6-C6H6)2] with Tl[TlC2B9H11] affords closo-[3-(η6-C6H6)-3,1,2-RuC2B9H11](7). Complexes (2) and (7) have been characterised by single-crystal X-ray diffraction. Crystals of (2) are orthorhombic, space group Pna21, with a= 21.793(4), b= 8.6274(15), c= 8.636(3){\AA}, and Z= 4; R= 0.0499 for 1 676 reflections. Complex (7) is also orthorhombic, space group Pnam, with a= 18.477(2), b= 9.191(4), and c= 7.704(1){\AA}, and Z= 4; R= 0.0223 for 1 723 data. Both species have slightly distorted Icosahedral cage geometries and overall Cs molecular symmetry, space group imposed for (7). The naphthalene derivative [1-(η6-C10H8)-2,4-Me2-1,2,4-FeC2B9H9] undergoes substitution of the arene ligand by CO at 100 bar and 50 °C, to afford the complex [1,1,1-(CO)3-2,4-Me2-1,2,4 FeC2B9H9].",
author = "Garcia, {Maria P.} and Michael Green and Stone, {F. Gordon A.} and Somerville, {Richard G.} and Welch, {Alan J.} and Briant, {Clive E.} and David Cox and Mingos, {D. Michael P.}",
year = "1985",
doi = "10.1039/dt9850002343",
language = "English",
volume = "1985",
pages = "2343--2348",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "11",

}

RIS

TY - JOUR

T1 - Metallaborane Chemistry. 14. Icosahedral 6-arene carbametallaboranes of iron and ruthenium

AU - Garcia, Maria P.

AU - Green, Michael

AU - Stone, F. Gordon A.

AU - Somerville, Richard G.

AU - Welch, Alan J.

AU - Briant, Clive E.

AU - Cox, David

AU - Mingos, D. Michael P.

PY - 1985

Y1 - 1985

N2 - Icosahedral 2,4-dicarba-1-ferraboranes with η6-bonded benzene, toluene, o-xylene, or naphthalene ligands have been synthesised in moderate yields by reaction of [Fe(cod)(η5-C5H5)](cod = cyclo-octa-1,5-diene) with 2,3-Me2-2,3-C2B9H9 in the presence of the appropriate arene. In addition, the toluene derivative, closo-[1-(η6-C6H5Me)-2,4-Me2-1,2,4-FeC2B9H9](2), has also been obtained by treatment of the carbaborane with [Fe2(µ-η-C6Me6)(η5-C5H5)2] in toluene. Reaction of [RuCl2(η6-C6H6)2] with Tl[TlC2B9H11] affords closo-[3-(η6-C6H6)-3,1,2-RuC2B9H11](7). Complexes (2) and (7) have been characterised by single-crystal X-ray diffraction. Crystals of (2) are orthorhombic, space group Pna21, with a= 21.793(4), b= 8.6274(15), c= 8.636(3)Å, and Z= 4; R= 0.0499 for 1 676 reflections. Complex (7) is also orthorhombic, space group Pnam, with a= 18.477(2), b= 9.191(4), and c= 7.704(1)Å, and Z= 4; R= 0.0223 for 1 723 data. Both species have slightly distorted Icosahedral cage geometries and overall Cs molecular symmetry, space group imposed for (7). The naphthalene derivative [1-(η6-C10H8)-2,4-Me2-1,2,4-FeC2B9H9] undergoes substitution of the arene ligand by CO at 100 bar and 50 °C, to afford the complex [1,1,1-(CO)3-2,4-Me2-1,2,4 FeC2B9H9].

AB - Icosahedral 2,4-dicarba-1-ferraboranes with η6-bonded benzene, toluene, o-xylene, or naphthalene ligands have been synthesised in moderate yields by reaction of [Fe(cod)(η5-C5H5)](cod = cyclo-octa-1,5-diene) with 2,3-Me2-2,3-C2B9H9 in the presence of the appropriate arene. In addition, the toluene derivative, closo-[1-(η6-C6H5Me)-2,4-Me2-1,2,4-FeC2B9H9](2), has also been obtained by treatment of the carbaborane with [Fe2(µ-η-C6Me6)(η5-C5H5)2] in toluene. Reaction of [RuCl2(η6-C6H6)2] with Tl[TlC2B9H11] affords closo-[3-(η6-C6H6)-3,1,2-RuC2B9H11](7). Complexes (2) and (7) have been characterised by single-crystal X-ray diffraction. Crystals of (2) are orthorhombic, space group Pna21, with a= 21.793(4), b= 8.6274(15), c= 8.636(3)Å, and Z= 4; R= 0.0499 for 1 676 reflections. Complex (7) is also orthorhombic, space group Pnam, with a= 18.477(2), b= 9.191(4), and c= 7.704(1)Å, and Z= 4; R= 0.0223 for 1 723 data. Both species have slightly distorted Icosahedral cage geometries and overall Cs molecular symmetry, space group imposed for (7). The naphthalene derivative [1-(η6-C10H8)-2,4-Me2-1,2,4-FeC2B9H9] undergoes substitution of the arene ligand by CO at 100 bar and 50 °C, to afford the complex [1,1,1-(CO)3-2,4-Me2-1,2,4 FeC2B9H9].

U2 - 10.1039/dt9850002343

DO - 10.1039/dt9850002343

M3 - Journal article

VL - 1985

SP - 2343

EP - 2348

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 11

ER -