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Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT)

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT). / Caetano, M.; Correia dos Santos, M.M.; Rosa, N. et al.
In: Marine Pollution Bulletin, Vol. 179, 113715, 30.06.2022.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Caetano, M, Correia dos Santos, MM, Rosa, N, Carvalho, I, Rodríguez, JG, Belzunce-Segarra, MJ, Menchaca, I, Larreta, J, Sanz, MR, Millán-Gabet, V, Gonzalez, J-L, Amouroux, I, Guesdon, S, Menet-Nédélec, F, White, B, Regan, F, Nolan, M, McHugh, B, Bersuder, P, Bolam, T, Robinson, CD, Fones, GR, Zhang, H, Schintu, M, Montero, N & Marras, B 2022, 'Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT)', Marine Pollution Bulletin, vol. 179, 113715. https://doi.org/10.1016/j.marpolbul.2022.113715

APA

Caetano, M., Correia dos Santos, M. M., Rosa, N., Carvalho, I., Rodríguez, J. G., Belzunce-Segarra, M. J., Menchaca, I., Larreta, J., Sanz, M. R., Millán-Gabet, V., Gonzalez, J.-L., Amouroux, I., Guesdon, S., Menet-Nédélec, F., White, B., Regan, F., Nolan, M., McHugh, B., Bersuder, P., ... Marras, B. (2022). Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT). Marine Pollution Bulletin, 179, Article 113715. https://doi.org/10.1016/j.marpolbul.2022.113715

Vancouver

Caetano M, Correia dos Santos MM, Rosa N, Carvalho I, Rodríguez JG, Belzunce-Segarra MJ et al. Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT). Marine Pollution Bulletin. 2022 Jun 30;179:113715. Epub 2022 May 6. doi: 10.1016/j.marpolbul.2022.113715

Author

Caetano, M. ; Correia dos Santos, M.M. ; Rosa, N. et al. / Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT). In: Marine Pollution Bulletin. 2022 ; Vol. 179.

Bibtex

@article{b5297f0ad70443d4a552caf2f078e0de,
title = "Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT)",
abstract = "This study investigates the relationships among Ni, Cd and Pb's different chemical forms determined by different methodologies in coastal and transitional waters across a broad geographical scale. Concentrations were measured in spot samples and through passive sampling (DGT). High variability of metal concentrations was found among sampling sites and methodologies due to natural water fluctuations rather than to a given metal or method. Total dissolved metal concentrations in spot samples were lower than the EQS-WFD values. The labile fractions of Cd and Pb, measured in spot samples by Anodic Stripping Voltammetry and by DGT-ICPMS, were highly correlated. Similar labilities were found for Cd, while for Pb, the ASV labile fraction was ≈50% lower. These results reflect the pool of mobile and labile species available towards each technique kinetic window, and they seem not to be affected by discrete sampling flaws. ",
keywords = "Broad geographical scale, DGT, European coastal and transitional waters, Priority metals, Voltammetry",
author = "M. Caetano and {Correia dos Santos}, M.M. and N. Rosa and I. Carvalho and J.G. Rodr{\'i}guez and M.J. Belzunce-Segarra and I. Menchaca and J. Larreta and M.R. Sanz and V. Mill{\'a}n-Gabet and J.-L. Gonzalez and I. Amouroux and S. Guesdon and F. Menet-N{\'e}d{\'e}lec and B. White and F. Regan and M. Nolan and B. McHugh and P. Bersuder and T. Bolam and C.D. Robinson and G.R. Fones and H. Zhang and M. Schintu and N. Montero and B. Marras",
year = "2022",
month = jun,
day = "30",
doi = "10.1016/j.marpolbul.2022.113715",
language = "English",
volume = "179",
journal = "Marine Pollution Bulletin",
issn = "0025-326X",
publisher = "Elsevier Ltd",

}

RIS

TY - JOUR

T1 - Metals concentrations in transitional and coastal waters by ICPMS and voltammetry analysis of spot samples and passive samplers (DGT)

AU - Caetano, M.

AU - Correia dos Santos, M.M.

AU - Rosa, N.

AU - Carvalho, I.

AU - Rodríguez, J.G.

AU - Belzunce-Segarra, M.J.

AU - Menchaca, I.

AU - Larreta, J.

AU - Sanz, M.R.

AU - Millán-Gabet, V.

AU - Gonzalez, J.-L.

AU - Amouroux, I.

AU - Guesdon, S.

AU - Menet-Nédélec, F.

AU - White, B.

AU - Regan, F.

AU - Nolan, M.

AU - McHugh, B.

AU - Bersuder, P.

AU - Bolam, T.

AU - Robinson, C.D.

AU - Fones, G.R.

AU - Zhang, H.

AU - Schintu, M.

AU - Montero, N.

AU - Marras, B.

PY - 2022/6/30

Y1 - 2022/6/30

N2 - This study investigates the relationships among Ni, Cd and Pb's different chemical forms determined by different methodologies in coastal and transitional waters across a broad geographical scale. Concentrations were measured in spot samples and through passive sampling (DGT). High variability of metal concentrations was found among sampling sites and methodologies due to natural water fluctuations rather than to a given metal or method. Total dissolved metal concentrations in spot samples were lower than the EQS-WFD values. The labile fractions of Cd and Pb, measured in spot samples by Anodic Stripping Voltammetry and by DGT-ICPMS, were highly correlated. Similar labilities were found for Cd, while for Pb, the ASV labile fraction was ≈50% lower. These results reflect the pool of mobile and labile species available towards each technique kinetic window, and they seem not to be affected by discrete sampling flaws.

AB - This study investigates the relationships among Ni, Cd and Pb's different chemical forms determined by different methodologies in coastal and transitional waters across a broad geographical scale. Concentrations were measured in spot samples and through passive sampling (DGT). High variability of metal concentrations was found among sampling sites and methodologies due to natural water fluctuations rather than to a given metal or method. Total dissolved metal concentrations in spot samples were lower than the EQS-WFD values. The labile fractions of Cd and Pb, measured in spot samples by Anodic Stripping Voltammetry and by DGT-ICPMS, were highly correlated. Similar labilities were found for Cd, while for Pb, the ASV labile fraction was ≈50% lower. These results reflect the pool of mobile and labile species available towards each technique kinetic window, and they seem not to be affected by discrete sampling flaws.

KW - Broad geographical scale

KW - DGT

KW - European coastal and transitional waters

KW - Priority metals

KW - Voltammetry

U2 - 10.1016/j.marpolbul.2022.113715

DO - 10.1016/j.marpolbul.2022.113715

M3 - Journal article

VL - 179

JO - Marine Pollution Bulletin

JF - Marine Pollution Bulletin

SN - 0025-326X

M1 - 113715

ER -