Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Miniaturised isotachophoretic analysis of inorganic arsenic speciation using a planar polymer chip with integrated conductivity detection
AU - Prest, J. E.
AU - Baldock, S. J.
AU - Fielden, P. R.
AU - Goddard, N. J.
AU - Brown, B. J. T.
PY - 2003
Y1 - 2003
N2 - A new method allowing the analysis of inorganic arsenic species using isotachophoresis has been developed. This method has been shown to be suitable for use on both miniaturised planar polymer separation devices and capillary scale devices. A poly(methyl methacrylate) chip with integrated conductivity electrodes has been successfully used for the rapid analysis of inorganic arsenic species in under 600 s. Limits of detection of 1.8 mg l−1 and 4.8 mg l−1 for arsenic(V) and arsenic(III), respectively, have been achieved with the miniaturised device. The device has also been used to perform the simultaneous separation of arsenic(III), arsenic(V), antimony(III), molybdenum(VI) and tellurium(IV).
AB - A new method allowing the analysis of inorganic arsenic species using isotachophoresis has been developed. This method has been shown to be suitable for use on both miniaturised planar polymer separation devices and capillary scale devices. A poly(methyl methacrylate) chip with integrated conductivity electrodes has been successfully used for the rapid analysis of inorganic arsenic species in under 600 s. Limits of detection of 1.8 mg l−1 and 4.8 mg l−1 for arsenic(V) and arsenic(III), respectively, have been achieved with the miniaturised device. The device has also been used to perform the simultaneous separation of arsenic(III), arsenic(V), antimony(III), molybdenum(VI) and tellurium(IV).
KW - Isotachophoresis
KW - Chip technology
KW - Instrumentation
KW - Conductivity detection
KW - Detection, electrophoresis
KW - Inorganic anions
KW - Arsenic
U2 - 10.1016/s0021-9673(02)01968-4
DO - 10.1016/s0021-9673(02)01968-4
M3 - Journal article
VL - 990
SP - 325
EP - 334
JO - Journal of Chromatography A
JF - Journal of Chromatography A
SN - 0021-9673
IS - 1-2
ER -