Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Modification of polyethylene glycol with choline chloride and evaluation of the CO2 absorption capacity of their aqueous solutions
AU - Sadeghpour, Mahsa
AU - Yusoff, Rozita
AU - Aroua, Mohamed Kheireddine
AU - Tabandeh, Mojtaba
PY - 2018/4/1
Y1 - 2018/4/1
N2 - In this study, two new water-soluble poly ionic liquids (PILs) polyethylene glycol- Di choline chloride (PEG-(ChCl)2) were modified, with two molecular weights of PEG, 400 and 600, to be used as solvents for CO2 capture. The modified polymers were characterized using Fourier transform infra-red (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H-NMR). CO2 absorption using the PILs was conducted at temperatures from 30 to 70°C and at pressures ranging from 10 to 13 bars. Both PILs saturated and then regenerated under the regeneration temperature: 90–100°C. The results showed that most of CO2 in the liquid phase is released through the thermal regeneration before solutions start to boil after three cycles. PEG (400)–(ChCl)2, and PEG(600)–(ChCl)2 with a concentration of 0.03M showed CO2 loading of 16.24 and 15.68, respectively. These results were 25% higher than the original PEG (400–600).
AB - In this study, two new water-soluble poly ionic liquids (PILs) polyethylene glycol- Di choline chloride (PEG-(ChCl)2) were modified, with two molecular weights of PEG, 400 and 600, to be used as solvents for CO2 capture. The modified polymers were characterized using Fourier transform infra-red (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H-NMR). CO2 absorption using the PILs was conducted at temperatures from 30 to 70°C and at pressures ranging from 10 to 13 bars. Both PILs saturated and then regenerated under the regeneration temperature: 90–100°C. The results showed that most of CO2 in the liquid phase is released through the thermal regeneration before solutions start to boil after three cycles. PEG (400)–(ChCl)2, and PEG(600)–(ChCl)2 with a concentration of 0.03M showed CO2 loading of 16.24 and 15.68, respectively. These results were 25% higher than the original PEG (400–600).
KW - choline chloride
KW - CO absorption
KW - poly ionic liquids
KW - polyethylene glycol
U2 - 10.1002/ghg.1741
DO - 10.1002/ghg.1741
M3 - Journal article
AN - SCOPUS:85033225976
VL - 8
SP - 324
EP - 334
JO - Greenhouse Gases: Science and Technology
JF - Greenhouse Gases: Science and Technology
SN - 2152-3878
IS - 2
ER -