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NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols

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<mark>Journal publication date</mark>28/11/2013
<mark>Journal</mark>Organic and Biomolecular Chemistry
Issue number44
Volume11
Number of pages5
Pages (from-to)7662-7666
Publication StatusPublished
Early online date3/10/13
<mark>Original language</mark>English

Abstract

A base mediated isomerisation–allylation protocol of 1,3-disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway.