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Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control. / Huynh, T.M.T.; Phan, T.H.; Ivasenko, O. et al.
In: Nanoscale, Vol. 9, No. 1, 07.01.2017, p. 362-368.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Huynh, TMT, Phan, TH, Ivasenko, O, Mertens, SFL & De Feyter, S 2017, 'Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control', Nanoscale, vol. 9, no. 1, pp. 362-368. https://doi.org/10.1039/c6nr07519c

APA

Huynh, T. M. T., Phan, T. H., Ivasenko, O., Mertens, S. F. L., & De Feyter, S. (2017). Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control. Nanoscale, 9(1), 362-368. https://doi.org/10.1039/c6nr07519c

Vancouver

Huynh TMT, Phan TH, Ivasenko O, Mertens SFL, De Feyter S. Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control. Nanoscale. 2017 Jan 7;9(1):362-368. Epub 2016 Dec 7. doi: 10.1039/c6nr07519c

Author

Huynh, T.M.T. ; Phan, T.H. ; Ivasenko, O. et al. / Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control. In: Nanoscale. 2017 ; Vol. 9, No. 1. pp. 362-368.

Bibtex

@article{91027ba2fe0b4c788f6ff873be87b218,
title = "Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control",
abstract = "Highly oriented pyrolytic graphite (HOPG) can be covalently grafted with aryl radicals generated via the electrochemical reduction of 3,5-bis-tert-butyl-diazonium cations (3,5-TBD). The structure of the grafted layer and its stability under electrochemical conditions were assessed with electrochemical scanning tunneling microscopy (EC-STM) and cyclic voltammetry (CV). Stable within a wide (>2.5 V) electrochemical window, the grafted species can be locally removed using EC-STM-tip nanolithography. Using dibenzyl viologen as an example, we show that the generated nanocorrals of bare graphitic surface can be used to study nucleation and growth of self-assembled structures under conditions of nanoconfinement and electrochemical potential control. {\textcopyright} 2017 The Royal Society of Chemistry.",
keywords = "Cyclic voltammetry, Electrolytic reduction, Scanning tunneling microscopy, Self assembly, Electrochemical conditions, Electrochemical control, Electrochemical potential, Electrochemical reductions, Electrochemical scanning tunneling microscopy, Electrochemical window, Highly oriented pyrolytic graphite, Self assembled structures, Grafting (chemical)",
author = "T.M.T. Huynh and T.H. Phan and O. Ivasenko and S.F.L. Mertens and {De Feyter}, S.",
year = "2017",
month = jan,
day = "7",
doi = "10.1039/c6nr07519c",
language = "English",
volume = "9",
pages = "362--368",
journal = "Nanoscale",
issn = "2040-3364",
publisher = "Royal Society of Chemistry",
number = "1",

}

RIS

TY - JOUR

T1 - Nanoconfined self-assembly on a grafted graphitic surface under electrochemical control

AU - Huynh, T.M.T.

AU - Phan, T.H.

AU - Ivasenko, O.

AU - Mertens, S.F.L.

AU - De Feyter, S.

PY - 2017/1/7

Y1 - 2017/1/7

N2 - Highly oriented pyrolytic graphite (HOPG) can be covalently grafted with aryl radicals generated via the electrochemical reduction of 3,5-bis-tert-butyl-diazonium cations (3,5-TBD). The structure of the grafted layer and its stability under electrochemical conditions were assessed with electrochemical scanning tunneling microscopy (EC-STM) and cyclic voltammetry (CV). Stable within a wide (>2.5 V) electrochemical window, the grafted species can be locally removed using EC-STM-tip nanolithography. Using dibenzyl viologen as an example, we show that the generated nanocorrals of bare graphitic surface can be used to study nucleation and growth of self-assembled structures under conditions of nanoconfinement and electrochemical potential control. © 2017 The Royal Society of Chemistry.

AB - Highly oriented pyrolytic graphite (HOPG) can be covalently grafted with aryl radicals generated via the electrochemical reduction of 3,5-bis-tert-butyl-diazonium cations (3,5-TBD). The structure of the grafted layer and its stability under electrochemical conditions were assessed with electrochemical scanning tunneling microscopy (EC-STM) and cyclic voltammetry (CV). Stable within a wide (>2.5 V) electrochemical window, the grafted species can be locally removed using EC-STM-tip nanolithography. Using dibenzyl viologen as an example, we show that the generated nanocorrals of bare graphitic surface can be used to study nucleation and growth of self-assembled structures under conditions of nanoconfinement and electrochemical potential control. © 2017 The Royal Society of Chemistry.

KW - Cyclic voltammetry

KW - Electrolytic reduction

KW - Scanning tunneling microscopy

KW - Self assembly

KW - Electrochemical conditions

KW - Electrochemical control

KW - Electrochemical potential

KW - Electrochemical reductions

KW - Electrochemical scanning tunneling microscopy

KW - Electrochemical window

KW - Highly oriented pyrolytic graphite

KW - Self assembled structures

KW - Grafting (chemical)

U2 - 10.1039/c6nr07519c

DO - 10.1039/c6nr07519c

M3 - Journal article

VL - 9

SP - 362

EP - 368

JO - Nanoscale

JF - Nanoscale

SN - 2040-3364

IS - 1

ER -