New platinum-catalysed dihydroalkoxylation of allenes

Chemistry

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https://doi.org/10.1002/adsc.201000342
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New platinum-catalysed dihydroalkoxylation of allenes. / Munoz-Herranz, Maria; de la Torre, María C.; Sierra, Miguel A.
In: Advanced Synthesis & Catalysis, Vol. 352, No. 13, 07.09.2010, p. 2189-2194.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Munoz-Herranz, M, de la Torre, MC & Sierra, MA 2010, 'New platinum-catalysed dihydroalkoxylation of allenes', Advanced Synthesis & Catalysis, vol. 352, no. 13, pp. 2189-2194. https://doi.org/10.1002/adsc.201000342

APA

Munoz-Herranz, M., de la Torre, M. C., & Sierra, M. A. (2010). New platinum-catalysed dihydroalkoxylation of allenes. Advanced Synthesis & Catalysis, 352(13), 2189-2194. https://doi.org/10.1002/adsc.201000342

Vancouver

Munoz-Herranz M, de la Torre MC, Sierra MA. New platinum-catalysed dihydroalkoxylation of allenes. Advanced Synthesis & Catalysis. 2010 Sept 7;352(13):2189-2194. doi: 10.1002/adsc.201000342

Author

Munoz-Herranz, Maria ; de la Torre, María C. ; Sierra, Miguel A. / New platinum-catalysed dihydroalkoxylation of allenes. In: Advanced Synthesis & Catalysis. 2010 ; Vol. 352, No. 13. pp. 2189-2194.

Bibtex

@article{5135da1d0e224744bb642914513eb4f8,

title = "New platinum-catalysed dihydroalkoxylation of allenes",

abstract = "A new platinum-catalysed dihydroalkoxylation of allenes is described to give aliphatic acetals by an unexpected attack of two molecules of methanol to the terminal carbon of the allene moiety. Deuteration experiments suggest an unprecedented formal 1,3-dipolar addition of methanol to a zwitterionic platinum carbene as the key step. The first platinum-catalysed intermolecular carbon-based nucleophile addition to allenes is also reported.",

author = "Maria Munoz-Herranz and {de la Torre}, {Mar{\'i}a C.} and Sierra, {Miguel A.}",

year = "2010",

month = sep,

day = "7",

doi = "10.1002/adsc.201000342",

language = "English",

volume = "352",

pages = "2189--2194",

journal = "Advanced Synthesis & Catalysis",

issn = "1615-4150",

publisher = "Wiley",

number = "13",

}

RIS

TY - JOUR

T1 - New platinum-catalysed dihydroalkoxylation of allenes

AU - Munoz-Herranz, Maria

AU - de la Torre, María C.

AU - Sierra, Miguel A.

PY - 2010/9/7

Y1 - 2010/9/7

N2 - A new platinum-catalysed dihydroalkoxylation of allenes is described to give aliphatic acetals by an unexpected attack of two molecules of methanol to the terminal carbon of the allene moiety. Deuteration experiments suggest an unprecedented formal 1,3-dipolar addition of methanol to a zwitterionic platinum carbene as the key step. The first platinum-catalysed intermolecular carbon-based nucleophile addition to allenes is also reported.

AB - A new platinum-catalysed dihydroalkoxylation of allenes is described to give aliphatic acetals by an unexpected attack of two molecules of methanol to the terminal carbon of the allene moiety. Deuteration experiments suggest an unprecedented formal 1,3-dipolar addition of methanol to a zwitterionic platinum carbene as the key step. The first platinum-catalysed intermolecular carbon-based nucleophile addition to allenes is also reported.

U2 - 10.1002/adsc.201000342

DO - 10.1002/adsc.201000342

M3 - Journal article

VL - 352

SP - 2189

EP - 2194

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

SN - 1615-4150

IS - 13

ER -

Research

Text available via DOI: