Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - New stepwise approach to inert heterometallic triple-stranded helicates
AU - Fletcher, Nicholas C.
AU - Brown, Rodney T.
AU - Doherty, Andrew P.
PY - 2006/8/7
Y1 - 2006/8/7
N2 - The new tripodal fac-functionalized building block, fac-ruthenium-(II) tris-(5-hydroxymethyl-2,2′-bipyridine), has been synthesized as a single geometric isomer and used as starting point in the isolation of a kinetically inert heterometallic helicate by the stepwise inclusion of additional 2,2′-bipyridine chelating groups followed by a second metal ion. This stepwise synthetic methodology gives access to a new range of chiral nanoscale structures inaccessible by traditional self-assembly procedures.
AB - The new tripodal fac-functionalized building block, fac-ruthenium-(II) tris-(5-hydroxymethyl-2,2′-bipyridine), has been synthesized as a single geometric isomer and used as starting point in the isolation of a kinetically inert heterometallic helicate by the stepwise inclusion of additional 2,2′-bipyridine chelating groups followed by a second metal ion. This stepwise synthetic methodology gives access to a new range of chiral nanoscale structures inaccessible by traditional self-assembly procedures.
U2 - 10.1021/ic060966x
DO - 10.1021/ic060966x
M3 - Journal article
AN - SCOPUS:33748271514
VL - 45
SP - 6132
EP - 6134
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 16
ER -