Nickel nanoparticle modified BDD electrode shows an electrocatalytic response to adenine and DNA in aqueous alkaline media

Chemistry

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https://doi.org/10.1002/elan.201000658
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Keywords

Boron doped diamond (BDD) electrode, DNA, Adenin, Electrochemical response, Ni-BDD electrode, DOPED-DIAMOND ELECTRODES, ELECTROCHEMICAL OXIDATION, LIQUID-CHROMATOGRAPHY, ACID, MICROELECTRODE, ADSORPTION, MECHANISM, PRODUCTS, GUANINE, ELECTROANALYSIS

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Nickel nanoparticle modified BDD electrode shows an electrocatalytic response to adenine and DNA in aqueous alkaline media. / Harfield, John C.; Toghill, Kathryn E.; Batchelor-McAuley, Christopher et al.
In: Electroanalysis, Vol. 23, No. 4, 04.2011, p. 931-938.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Bibtex

@article{cbbc9d117ebb45feafe44ddc9495f798,

title = "Nickel nanoparticle modified BDD electrode shows an electrocatalytic response to adenine and DNA in aqueous alkaline media",

abstract = "The electrooxidation of adenine, guanine and DNA was investigated under alkaline conditions at unmodified (BDDE) and at a nickel nanoparticle modified boron-doped diamond electrodes (Ni-BDDE). An oxidative response was observed at the Ni-BDDE for each analyte, particularly notable of the adenine as the oxidation overpotential was reduced to below 0.5 V vs. SCE, and was otherwise unobserved at the unmodified electrode.",

keywords = "Boron doped diamond (BDD) electrode, DNA, Adenin, Electrochemical response, Ni-BDD electrode, DOPED-DIAMOND ELECTRODES, ELECTROCHEMICAL OXIDATION, LIQUID-CHROMATOGRAPHY, ACID, MICROELECTRODE, ADSORPTION, MECHANISM, PRODUCTS, GUANINE, ELECTROANALYSIS",

author = "Harfield, {John C.} and Toghill, {Kathryn E.} and Christopher Batchelor-McAuley and Clive Downing and Compton, {Richard G.}",

year = "2011",

month = apr,

doi = "10.1002/elan.201000658",

language = "English",

volume = "23",

pages = "931--938",

journal = "Electroanalysis",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

number = "4",

}

RIS

TY - JOUR

T1 - Nickel nanoparticle modified BDD electrode shows an electrocatalytic response to adenine and DNA in aqueous alkaline media

AU - Harfield, John C.

AU - Toghill, Kathryn E.

AU - Batchelor-McAuley, Christopher

AU - Downing, Clive

AU - Compton, Richard G.

PY - 2011/4

Y1 - 2011/4

N2 - The electrooxidation of adenine, guanine and DNA was investigated under alkaline conditions at unmodified (BDDE) and at a nickel nanoparticle modified boron-doped diamond electrodes (Ni-BDDE). An oxidative response was observed at the Ni-BDDE for each analyte, particularly notable of the adenine as the oxidation overpotential was reduced to below 0.5 V vs. SCE, and was otherwise unobserved at the unmodified electrode.

AB - The electrooxidation of adenine, guanine and DNA was investigated under alkaline conditions at unmodified (BDDE) and at a nickel nanoparticle modified boron-doped diamond electrodes (Ni-BDDE). An oxidative response was observed at the Ni-BDDE for each analyte, particularly notable of the adenine as the oxidation overpotential was reduced to below 0.5 V vs. SCE, and was otherwise unobserved at the unmodified electrode.

KW - Boron doped diamond (BDD) electrode

KW - DNA

KW - Adenin

KW - Electrochemical response

KW - Ni-BDD electrode

KW - DOPED-DIAMOND ELECTRODES

KW - ELECTROCHEMICAL OXIDATION

KW - LIQUID-CHROMATOGRAPHY

KW - ACID

KW - MICROELECTRODE

KW - ADSORPTION

KW - MECHANISM

KW - PRODUCTS

KW - GUANINE

KW - ELECTROANALYSIS

U2 - 10.1002/elan.201000658

DO - 10.1002/elan.201000658

M3 - Journal article

VL - 23

SP - 931

EP - 938

JO - Electroanalysis

JF - Electroanalysis

SN - 1040-0397

IS - 4

ER -

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